Results 221 to 230 of about 182,434 (289)

(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications

open access: yesAngewandte Chemie, EarlyView.
In this review, we spotlight recent breakthroughs in α‐polyboron‐substituted carbon‐centered intermediates (carbanion, carbocation, radical, and carbene) and polyborylated alkenes. By bridging fundamental reactivity with the application potential of these extraordinary species, we hope this review will serve as a roadmap for harnessing these unique ...
Nadim Eghbarieh   +5 more
wiley   +2 more sources

Toward Harmonizing Quantification of Dopamine Neuron Imaging Biomarkers in Parkinson's Disease: The Centamine Scale

open access: yesAnnals of Neurology, EarlyView.
Objective Dopaminergic imaging is a key biomarker for both the investigation of the biology of Parkinson's disease and related synucleinopathies and the evaluation of potential therapies in clinical trials. This work presents a harmonized approach for quantifying dopaminergic molecular imaging tracers, such as [123I]ioflupane (dopamine transporter scan
Zhen Fan   +174 more
wiley   +1 more source

A Crystalline Mono‐Coordinate Indium(I)‐Phosphaalkenyl

open access: yesAngewandte Chemie, EarlyView.
The redox neutral carbometallation of a phospha‐alkyne using the dimeric indium(I) compound (InTer)2 is reported. This reaction affords a mono‐coordinate indium(I) compound that can reversibly extrude the phospha‐alkyne upon addition of a Lewis acid. Abstract The synthesis of the mono‐coordinate indium(I) compound In[C(Ad)═PTer] (Ad = 1‐adamantyl, Ter =
Álvaro García‐Romero   +3 more
wiley   +2 more sources

[Postoperative result in appendectomy with Pouchet technique versus other surgical techniques]. [PDF]

open access: yesRev Med Inst Mex Seguro Soc
Hernández-Flores AJ   +6 more
europepmc   +1 more source

Diverse Genetic Etiologies of Unilateral Polymicrogyria

open access: yesAnnals of Neurology, EarlyView.
Objective Polymicrogyria (PMG) is one of the most common human malformations of cortical development and is often classified by its radiographic pattern of distribution. Unilateral polymicrogyria (uPMG) is a subtype of PMG affecting a portion or all of one cerebral hemisphere.
Abbe Lai   +21 more
wiley   +1 more source

Boosting the Nucleophilicity of the Diphenylphosphide Anion with Crown Ether Supported Heavy Alkali Metals to Facilitate Highly Efficient Catalytic Alkene Isomerisation

open access: yesAngewandte Chemie, EarlyView.
Here, we report a breakthrough study in catalytic alkene isomerisation using crown ether‐supported alkali metal phosphides in which the activity increases sequentially and significantly as Group One is descended with Cs(18‐crown‐6)PPh2 (1Cs) performing best.
Felix Krämer   +2 more
wiley   +2 more sources

Birth of a Language in the Backlands of Brazil. [PDF]

open access: yesCogn Sci
Almeida-Silva A   +4 more
europepmc   +1 more source

Reducing Interface Energy Loss of Perovskite Solar Cells by Molecular Engineering of Hole‐Transporting Materials

open access: yesAngewandte Chemie, EarlyView.
This study reports a new hole‐transporting material (WD03) designed via molecular engineering to regulate defect passivation and energy‐level alignment in perovskite solar cells (PSCs). The propeller‐shaped structure ensures balanced charge transport and film quality. Consequently, WD03‐based devices deliver a high open‐circuit voltage of 1.194 V under
Guang Shao   +17 more
wiley   +2 more sources

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