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Direct α‐Arylation of Ethers through the Combination of Photoredox‐Mediated CH Functionalization and the Minisci Reaction

open access: yesAngewandte Chemie - International Edition, 2015
The direct α-arylation of cyclic and acyclic ethers with heteroarenes has been accomplished through the design of a photoredox-mediated CH functionalization pathway.
Jian Jin, Elfadil E Babiker
exaly   +2 more sources

Metal-catalyzed activation of ethers via C–O bond cleavage: a new strategy for molecular diversity

open access: yesChemical Society Reviews, 2014
In 1979, the seminal work of Wenkert set the standards for the utilization of aryl and vinyl ethers as coupling partners via C-O bond-cleavage. Although the topic remained dormant for almost three decades, the last few years have witnessed a renaissance ...
Josep Cornella, Ruben Martin
exaly   +2 more sources

Facile access to bicyclo[2.1.1]hexanes by Lewis acid-catalyzed formal cycloaddition between silyl enol ethers and bicyclo[1.1.0]butanes [PDF]

open access: yesNature Communications
Saturated three-dimensional carbocycles have gained increasing prominence in synthetic and medicinal chemistry. In particular, bicyclo[2.1.1]hexanes (BCHs) have been identified as the molecular replacement for benzenes.
Sai Hu, Yuming Pan, Dongshun Ni, Li Deng
doaj   +2 more sources

Platform Chemicals from Ethylene Glycol and Isobutene: Thermodynamics “Pays” for Biomass Valorisation and Acquires “Cashback”

open access: yesChemistry, 2023
Ethylene glycol (EG) produced from biomass is a promising candidate for several new applications. In this paper, EG derivatives such as mono- and di-tert-butyl ethers are considered.
Sergey P. Verevkin   +1 more
doaj   +1 more source

Effect of organic compounds on cognac sensory profile

open access: yesFoods and Raw Materials, 2021
Introduction. The present research featured the effect of carbonyls, phenols, furans, fatty alcohols, ethers, and other chemical compounds on the sensory properties of cognac distillates of different ages.
Mikhail N. Eliseev   +3 more
doaj   +1 more source

Methyl and Ethyl Ethers of Glycerol as Potential Green Low-Melting Technical Fluids

open access: yesMolecules, 2023
The study is dedicated to the consideration of lower alkyl ethers of glycerol as potential components of low-melting technical fluids (e.g., heat transfer fluids, hydraulic fluids, aircraft de-icing fluids, etc.).
Vadim Samoilov   +7 more
doaj   +1 more source

Densities, refractive indices and viscosities of the binary mixtures of dimethyl phthalate or dimethyl adipate with tetrahydrofuran [PDF]

open access: yesJournal of the Serbian Chemical Society, 2014
Densities, refractive indices and viscosities of the binary mixtures of dimethyl phthalate (or dimethyl adipate) + tetrahydrofuran have been measured at eight temperatures (288.15 to 323.15 K) and atmospheric pressure.
Knežević-Stevanović Anđela B.   +4 more
doaj   +1 more source

Electrophotocatalytic C-H Functionalization of Ethers with High Regioselectivity.

open access: yesJournal of the American Chemical Society, 2020
The highly regioselective electrophotocatalytic C-H functionalization of ethers is described. These reactions are catalyzed by a trisaminocyclopropenium (TAC) ion in a mild electrochemical potential with visible light irradiation.
He Huang, Z. Strater, T. Lambert
semanticscholar   +1 more source

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