Results 101 to 110 of about 12,704 (308)

Reaction engineering blocks ether cleavage for synthesizing chiral cyclic hemiacetals catalyzed by unspecific peroxygenase

open access: yesNature Communications
Hemiacetal compounds are valuable building blocks in synthetic chemistry, but their enzymatic synthesis is limited and often hindered by the instability of hemiacetals in aqueous environments.
Xiaofeng Han   +7 more
doaj   +1 more source

Surface‐Functionalized LLZO‐Incorporated Multilayer Composite Solid Electrolytes for Dendrite Suppression and Efficient Ionic Conduction in Lithium–Metal Batteries

open access: yesAdvanced Materials, EarlyView.
A soft–hard tri‐layer composite electrolyte that couples fast Li+ transport with reinforced interfacial stability to enable high‐conductivity, mechanically robust, dendrite‐free lithium‐metal batteries. ABSTRACT The development of solid polymer electrolytes is central to safe, high‐energy lithium‐metal batteries (LMBs); however, persistent challenges ...
Fazal Ur Rehman   +9 more
wiley   +1 more source

Conformational Bias by a Removable Substituent. Synthesis of Eight-Membered Cyclic Ethers via Ring-Closing Metathesis [PDF]

open access: yes, 2016
Conformational Bias by a Removable Substituent.
Stacy A. O'Neil (3001377)   +3 more
core   +1 more source

Multicomponent versus domino reactions: One-pot free-radical synthesis of β-amino-ethers and β-amino-alcohols

open access: yesBeilstein Journal of Organic Chemistry, 2015
Following an optimized multicomponent procedure, an aryl amine, a ketone, and a cyclic ether or an alcohol molecule are assembled in a one-pot synthesis by nucleophilic radical addition of ketyl radicals to ketimines generated in situ.
Bianca Rossi   +3 more
doaj   +1 more source

Taming Hypervalent Bonds and Strained Rings for Catalysis and Synthesis

open access: yesCHIMIA, 2014
Improving the synthesis of complex organic molecules is essential for progress in many fields such as medicine, agrochemicals or materials. Since 2007, our laboratory has been focusing on the development of non-classical bond disconnections ...
Florian de Nanteuil   +6 more
doaj   +1 more source

Solvent‐Guided Chiral Assemblies and Chemical Doping of OEG‐Functionalized Conjugated Polymers

open access: yesAdvanced Materials, EarlyView.
Solvent‐dependent aggregation pathways dictate whether conjugated polymers form chiral lyotropic liquid‐crystalline assemblies or achiral packed aggregates. Mapping solvent‐controlled β₁ and β2 states reveals that weaker backbone association favors β₁ aggregates and reorganizable twisted mesophases, whereas stronger backbone association favors β2 ...
Sanghyun Jeon   +10 more
wiley   +1 more source

Platinum complexes with imino ethers or cyclic ligands mimicking imino ethers: synthesis, in vitro antitumour activity, and DNA interaction properties [PDF]

open access: yes, 2004
Both trans- and CiS-[PtCl2(NH3)(L)] compounds have been synthesized, L representing either the imino ether HN = C(OMe)Me having a Z or E configuration at the C = N double bond, or the cyclic ligands N = C(OMe)CH2CH2CH2 and C(Me)OCH2CH2 (compounds 1-4 ...
FRANCIA VC   +8 more
core   +1 more source

Navigating Lipid Nanostructure Design Space Through Continuous Microfluidic Automation

open access: yesAdvanced Materials, EarlyView.
LipidXplorer is a novel microfluidic platform which enables rapid navigation of lipid particle design space for high‐resolution phase mapping, lipid nanoparticle optimization, membrane biophysics, and functional nanomaterial discovery. It combines programmable composition control, continuous nanoparticle formation, and automated well‐plate collection ...
Bradley Diggines   +10 more
wiley   +1 more source

Asymmetric Lamellar Templating of the Perovskite/C60 Interface for Scalable Inverted Perovskite Photovoltaics

open access: yesAdvanced Materials, EarlyView.
Asymmetric lamellar templating at the perovskite/C60 interface is achieved using a laterally polarized indole spacer. Surface anchoring and Ind–Ind assembly form a π‐rich lamellar interphase that supports uniform C60 contact formation, suppresses recombination, preserves electron extraction, and enables certified high‐efficiency cells and modules with ...
Taeyoon Ki   +16 more
wiley   +1 more source

Gold(I)/(III)-Catalyzed Synthesis of Cyclic Ethers; Valency-Controlled Cyclization Modes [PDF]

open access: yes, 2016
Strategic use of oxophilic (hard) gold­(III) and π-philic (soft) gold­(I) catalysts provides access to two types of cyclic ethers from propargylic alcohols.
Nobuyoshi Morita (1608451)   +6 more
core   +1 more source

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