Results 91 to 100 of about 12,676 (308)

Cyclic ether

open access: yes, 2013
A process for preparing cyclic ethers is described. The process involves the reaction of at least one organic compound such as diols or polyol which it has at least one pair of hydroxyl groups separated by 5 or 5 carbon atoms, and which is capable of being converted into an ether linkage, with an organic carbonate in the presence of a base. The base is
H. Bevinakatti   +5 more
openaire   +1 more source

2D MOF with Intrinsic Porosity for Colorimetric Volatile Organic Compounds (VOCs) Detection

open access: yesAdvanced Materials, EarlyView.
An uncommon 2D MOF with intrinsic in‐plane porosity that can be mechanically exfoliated undergoes a distinct and reversible colour change upon exposure to various volatile organic compounds. ABSTRACT In this work, we report an uncommon 2D metal–organic framework (MOF) with intrinsic in‐plane porosity that undergoes a distinct and reversible colour ...
Sergio R. Gamarra   +4 more
wiley   +1 more source

Multicomponent versus domino reactions: One-pot free-radical synthesis of β-amino-ethers and β-amino-alcohols

open access: yesBeilstein Journal of Organic Chemistry, 2015
Following an optimized multicomponent procedure, an aryl amine, a ketone, and a cyclic ether or an alcohol molecule are assembled in a one-pot synthesis by nucleophilic radical addition of ketyl radicals to ketimines generated in situ.
Bianca Rossi   +3 more
doaj   +1 more source

Taming Hypervalent Bonds and Strained Rings for Catalysis and Synthesis

open access: yesCHIMIA, 2014
Improving the synthesis of complex organic molecules is essential for progress in many fields such as medicine, agrochemicals or materials. Since 2007, our laboratory has been focusing on the development of non-classical bond disconnections ...
Florian de Nanteuil   +6 more
doaj   +1 more source

A detailed cyclic ether oxidation mechanism for tetrahydrofuran radicals: A theoretical study

open access: yes, 2017
Cyclic ethers are important intermediate products in combustion, in atmospheric oxidation of hydrocarbons, and in the oxidation of biomass derived alcohols.
Sarathy, Mani, Wang, Heng
core  

Stereoselective Synthesis of Cyclic Ethers by Intramolecular Trapping of Dicobalt Hexacarbonyl-Stabilized Propargylic Cations

open access: yes, 2016
The intramolecular attack of a hydroxy group on an exo-biscobalthexacarbonyl propargylic cation provides cyclic ethers with six- to nine-membered rings. The scope and limitations of the methodology are described.
Tomás Martín (2453179)   +3 more
core   +1 more source

New‐Era Polymer Thermoelectrics: Material Innovations, Doping Frontiers, Decoupling Strategies, and Unconventional Applications

open access: yesAdvanced Materials, EarlyView.
The field of polymer thermoelectrics is entering a new era, featuring breakthroughs in addressing the conventional performance disparity between p‐type and n‐type polymers, pioneering doping frontiers, and sophisticated decoupling strategies. This review explores innovations in molecular design and superior stabilities, bridging the gap from ...
Suhao Wang
wiley   +1 more source

Neuromorphic Electronics for Intelligence Everywhere: Emerging Devices, Flexible Platforms, and Scalable System Architectures

open access: yesAdvanced Materials, EarlyView.
The perspective presents an integrated view of neuromorphic technologies, from device physics to real‐time applicability, while highlighting the necessity of full‐stack co‐optimization. By outlining practical hardware‐level strategies to exploit device behavior and mitigate non‐idealities, it shows pathways for building efficient, scalable, and ...
Kapil Bhardwaj   +8 more
wiley   +1 more source

Characterization of an unusual specific interaction between aromatic cyclic cis-vicinal triketones and cyclic saturated ethers

open access: yes, 2001
The nature of an unusual specific interaction between aromatic cyclic cis-vicinal triketone (I, II, III in Fig. 1) and cyclic saturated ethers (tetrahydrofuran and 2-methyl tetrahydrofuran) in the ground state has been explored using detailed AM1 ...
Sanjib Ghosh   +5 more
core   +1 more source

Clustomesogen Showing Sub‐Zero Liquid Crystal Properties: Supramolecular Assembly Between Cs2[Mo6Ii8(OCOC2F5)6] and Hexaethylenoxide Containing Mesogenic Dimers

open access: yesAdvanced Materials, EarlyView.
Associating a red‐NIR phosphorescent octahedral hexanuclear molybdenum cluster compound with hexaethyleneoxide chains bearing mesogenic units on both ends leads to an emissive hybrid liquid crystal showing mesomorphism on a very unusual temperature range down to −25°C.
Killiann Heinz   +11 more
wiley   +1 more source

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