Thermophysical properties of binary mixtures of N,N-dimethylformamide with three cyclic ethers [PDF]
Densities and viscosities of the binary mixtures consisting of tetrahydrofuran (THF), 1,3-dioxolane (1,3-DO) and 1,4-dioxane (1,4-DO) with N,N-dimethylformamide (DMF) over the entire range of composition were measured at temperatures 298.15, 308.15 ...
Sinha Biswajit +4 more
doaj +1 more source
Identification and quantitation of lipid-bound short-chain diols
Procedures are described for the hydrolysis of neutral lipid fractions containing long-chain esters and alk-1-enyl ethers of short-chain diols, and for the identification and quantitation of the constituent diols as long-chain cyclic acetals using gas ...
E. Schupp, W.J. Baumann
doaj +1 more source
Elusiveness of bishomoaromaticity in anionic systems: the bicyclo[3.2.1]octa-3,6-dien-2-yl anion [PDF]
This article does not have an ...
Chandrasekhar, Jayaraman +3 more
core +1 more source
Nickel-Catalyzed Carbonylative Synthesis of Functionalized Alkyl Iodides
Summary: Functionalized alkyl iodides are important compounds in organic chemistry and biology. In this communication, we developed an interesting nickel-catalyzed carbonylative synthesis of functionalized alkyl iodides from aryl iodides and ethers. With
Jin-Bao Peng +5 more
doaj +1 more source
Lewis acid catalyzed transfer hydromethallylation for the construction of quaternary carbon centers [PDF]
The design and gram‐scale synthesis of a cyclohexa‐1,4‐diene‐based surrogate of isobutene gas is reported. Using the highly electron‐deficient Lewis acid B(C6F5)3, application of this surrogate in the hydromethallylation of electron‐rich styrene ...
Oestreich, Martin +1 more
core +1 more source
Targeting TNBC: core–shell polycationic polyurea dendrimers with inherent anticancer activity
Core–shell polycationic PURE dendrimers were tested in TNBC‐derived tumor models. Both formulations selectively targeted TNBC and effectively reduced tumor volume. PUREG4‐OEI48 suppressed tumor growth without detectable toxicity, whereas PUREG4‐OCEI24, despite showing efficacy, induced hepatic toxicity.
Adriana Cruz +9 more
wiley +1 more source
High turnover in electro-oxidation of alcohols and ethers with a glassy carbon-supported phenanthroimidazole mediator. [PDF]
Glassy carbon electrodes covalently modified with a phenanthroimidazole mediator promote electrochemical alcohol and ether oxidation: three orders of magnitude increase in TON, to ∼15 000 in each case, was observed compared with homogeneous mediated ...
Berben, Louise A +3 more
core +1 more source
Amphiphilic Polyfluorinated Amino Ethers from Cyclic Sulfamidates
Regioselective ring opening of cyclic sulfamidates was achieved by means of nucleophilic polyfluorinated alkoxides to access achiral and chiral β- and γ-ORF amines and α-amino esters. Subsequent transformations provide free amines ready for incorporation into bioactive substances through amide bond formation or nucleophilic aromatic substitution.
Marie, Nicolas +2 more
openaire +4 more sources
Packaging of Macroscopic Material Payloads: Needs, Challenges, Concepts, and Future Directions
This review introduces a unified framework that decomposes any macroscopic packaging system into the payload, packaging material, and packaging strategy and combines them into a conceptual packaging equation: packaging strategy = payload + packaging material.
Venkata S. R. Jampani, Manos Anyfantakis
wiley +1 more source
Synthesis of pyrrolizines by intramolecular capture of 1,4-dipolar intermediates in reactions of enamines with dimethyl acetylenedicarboxylate [PDF]
Solvent polarity and reaction temperature strongly influence the reactions of dimethyl acetylenedicar-boxylate (DMAD) with 1-pyrrolidinyl enamines of acyclic and cyclic ketones. Whereas DMAD and 1-[1-phenyl-2-(phenylthio)ethenyl]pyrrolidine (3) give only
Harkema, S. +5 more
core +3 more sources

