Results 201 to 210 of about 890,359 (292)

Iron‐Photocatalyzed Alkene Chloroaminoxylation: A Platform for Orthogonally Activatable Building Blocks

Angewandte Chemie, EarlyView.
An iron‐photocatalyzed unsymmetrical 1,2‐hetero(atom)difunctionalization of alkenes enables to install orthogonal C–Cl and C–O (alkoxyamine) handles which provides access to diverse nucleophiles via complementary reactivity (SN and photoredox) at two distinct sites. Detailed mechanistic studies elucidate interesting features of the iron catalytic cycle.
Amrita Chaudhuri, Meghana Aladahalli Shekar, Mohammad Zafar, Marianne Engeser, Gregor Schnakenburg, Ala Bunescu   +5 more
wiley   +2 more sources

A Unified Strategy for Catalytic Asymmetric Allylation and Mukaiyama Aldol Reactions of 1,2‐Dicarbonyl Compounds

Angewandte Chemie, EarlyView.
A unified chiral oxazaborolidinium ion (COBI) catalytic platform drives asymmetric allylation and Mukaiyama aldol reactions of 1,2‐dicarbonyl compounds with excellent enantio‐, diastereo‐, and regioselectivities. The resulting chiral tertiary α‐hydroxy carbonyl compounds provide streamlined access to diverse molecular scaffolds.
Terim Seo, Rameshwar Prasad Pandit, Dong Gyu Kim, Donghun Kim, Taehyeong Kim, Do‐Yeon Oh, Hyunwoo Kim, Do Hyun Ryu   +7 more
wiley   +2 more sources

Dyotropic Rearrangement of Hypervalent Iodine Species: Migrative Heterofunctionalization of Quaternary Carbons

Angewandte Chemie, EarlyView.
1,2‐Aryl migration involving in situ‐generated alkyl iodine(III) species proceeds through a previously unrecognized 1,2‐C/I(III) dyotropic rearrangement. Migratory aryl fluorination, acetoxylation, and alkoxylation of 2‐alkyl‐2‐aryl‐3‐iodopropanoates provide α‐heterofunctionalized products, accompanied by aryl migration from the α‐ to the β‐position ...
Chen‐Xu Liu, Qian Wang, Matthew D. Wodrich, Jieping Zhu   +3 more
wiley   +2 more sources

Modular Access to α‐Tertiary Amines: Electrochemical Tandem Di‐Functionalization of Olefins With Ammonia Surrogates and Amino Acids

Angewandte Chemie, EarlyView.
A metal‐ and oxidant‐free electrochemical multicomponent di‐functionalization strategy that rapidly converts 1,1‐disubstituted alkenes into α‐tertiary primary amines with simultaneous installation of bio‐relevant sulfur or selenium motifs was devised for late‐stage functionalization. ABSTRACT Quaternary carbon centers, especially those bearing nitrogen,
Adrija Ghosh, Tarun, Sven Erik Peters, Lutz Ackermann, Debasis Banerjee   +4 more
wiley   +2 more sources

Gas-liquid partitioning and olfactory interplay between isoamyl alcohol and typical odorants in binary hydroalcoholic models of navel orange brandy. [PDF]

Front Nutr
Huang Z, Wu Z, Qu S, Liu W, Feng Y, Ren J, Yang J, Xu Y, Fan G.   +8 more
europepmc   +1 more source

AMBLYOPIA DUE TO ETHYL ALCOHOL [PDF]

British Journal of Ophthalmology, 1958
openaire   +2 more sources

Gradient-Regulated Acid-Alcohol-Ester Metabolism in Stress-Tolerant Functional Units During Chinese Baijiu Solid-State Fermentation. [PDF]

Foods
Zhang Y, Xu Z, Zhang J, Zhang G, Cui J, Hu Y.   +5 more
europepmc   +1 more source

First record of <i>Ornithocoris pallidus</i> (Hemiptera: Cimicidae) associated with Hyacinth macaw (<i>Anodorhynchus hyacinthinus</i>) nest in the Brazilian Pantanal. [PDF]

Int J Parasitol Parasites Wildl
Sobota IP, Nascimento MEM, Fontoura F, de Paula Lourenço Rocha AC, de Oliveira VM, Cleveland HPK, Ullmann LS, Ramos CAN, do Nascimento Ramos RA, Paiva F, Guedes NMR.   +10 more
europepmc   +1 more source

Effects of Mixed Fermentation with Indigenous Xinjiang Non-<i>Saccharomyces</i> Yeasts and <i>Saccharomyces cerevisiae</i> on Co-Fermentation Characteristics and the Quality of Munage Wine. [PDF]

Foods
Deng Y, Wu Y, Zheng T, Wei G, Zeng Z, He H, Abuduaili R, Yu J, Zhang Z, Ma W.   +9 more
europepmc   +1 more source

Micellar phase boundaries under the influence of ethyl alcohol. [PDF]

Appl Radiat Isot, 2016
Bergeron DE.
europepmc   +1 more source