Micellar phase boundaries under the influence of ethyl alcohol. [PDF]
Appl Radiat Isot, 2016 Bergeron DE.
europepmc +1 more source
Chemistry – A European Journal, EarlyView.T‐shaped bolapolyphiles with highly branched carbosilane‐based side‐groups self‐assemble into liquid crystalline honeycombs composed of type‐2 pentagonal prismatic cells and p2gg plane group symmetry. ABSTRACT Periodic pentagon tessellations are rarely observed in self‐assembled molecular systems.
Christian Anders +3 more
wiley +1 more source
Carboxylate–Probase Catalyzed Favorskii Reaction
Chemistry – A European Journal, EarlyView.Stronger together: A combination of a carboxylate catalyst and a silylating agent generates a stronger base catalyst for a metal‐free catalytic addition of alkynes to aldehydes and ketones under chemoselective, O‐silylative conditions. The reaction is proposed to proceed via quaternary ammonium (Q+) cation – acetylide anion ion pairs, with chiral ...
Anton Bannykh +4 more
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Molecular Sensory and GC-MS/MS Profiling of Key Aroma Compounds in Sauce-Flavor Base Baijiu. [PDF]
FoodsWang N +9 more
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Ir Complexes With Mixed‐Valent Bidentate Ligands: From Complex Synthesis to Catalytic Application
Chemistry – A European Journal, EarlyView.ABSTRACT The bidentate ligands Ph2P(E)NHPPh2 (E = S, Se) feature phosphorous atoms in two different oxidation states and provide the potential to tune chemical reactivity through the choice of donor E. The mononuclear complexes [Ir(COD){κ2‐P,E‐Ph2P(E)NPPh2}] (E = S 1a, Se 1b) were prepared from the dimer [IrClCOD]2 (COD = 1,5‐cyclooctadiene) and the ...
C. Gabriela Morales Salas +4 more
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Sparkling Winemaking Using the Achaean Grape Variety Sideritis and the Indigenous Yeast <i>Saccharomyces cerevisiae</i> ABET Isolated from Corinthian Currants: Chemical Composition, Quality Attributes, and Volatilome. [PDF]
FoodsAdamopoulou V +7 more
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C‐Terminal Functionalization Methods of Amino Acids, Peptides, and Proteins
Chemistry – A European Journal, EarlyView.C‐terminal functionalization offers powerful routes to peptide and protein diversification, yet epimerization, hydrolysis, and selectivity remain key challenges. This Review surveys enzymatic, decarboxylative, and condensation strategies, highlighting advances toward chemo‐ and regioselective, protecting‐group‐free, atom‐efficient methods applicable to
Jay Hanssens +3 more
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Alkyne‐Assisted Stereospecific Skeletal Rearrangement via Nonclassical Carbocations
Chemistry – A European Journal, EarlyView.We report stereospecific nucleophilic substitution of homopropargylic alcohols enabled by alkyne anchimeric assistance. Alcohol activation triggers formation of a nonclassical cyclopropylidenemethyl cation, allowing efficient chirality transfer to densely substituted tertiary homopropargyl fluorides.
Rajan Kumar Kharwar +3 more
wiley +1 more source
Gradient-Regulated Acid-Alcohol-Ester Metabolism in Stress-Tolerant Functional Units During Chinese Baijiu Solid-State Fermentation. [PDF]
FoodsZhang Y +5 more
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Modular Assembly of a Biocatalytic Material for Stereoselective C─Si Bond Formation
Chemistry – A European Journal, EarlyView.A modular, carrier‐free enzyme foam derived from Rhodothermus marinus cytochrome c combines structural stability with catalytic efficiency for stereoselective C─Si bond formation. Streptavidin (STV)‐mediated protein crosslinking creates a robust, self‐supporting materials platform for next‐generation biocatalysis.
Marc F. Münker +6 more
wiley +1 more source