A radical cascade process involving the activation of two aliphatic C–H bonds in a series of five elementary steps converts readily available terminal alkynes into functionalized cyclopentylmethyl arylsulfones. The methodology delivers flexible synthetic intermediates and was applied to the preparation of diquinanes and triquinanes possessing a rare ...
Lise Benoist +4 more
wiley +2 more sources
Environmental and Health Risk Assessments of Volatile Organic Compounds (VOCs) Based on Source Apportionment-A Case Study in Harbin, a Megacity in Northeastern China. [PDF]
Jiang J +7 more
europepmc +1 more source
Electric‐field‐induced chemistry at solid/vacuum interfaces offers precise control over chemical reactions. In this study, a triphenylmethane‐based tripod with a terminal alkyne is anchored upright on a gold surface. Advanced scanning tunneling microscopy and tip‐enhanced Raman scattering confirm the alignment and stability of the reactive center ...
Simon Mennicken +10 more
wiley +1 more source
Decoding the therapeutic potential mechanism of <i>Cornus officinalis</i> in Parkinson's disease: a network pharmacology insight. [PDF]
Wu Z +7 more
europepmc +1 more source
Ab Initio Molecular Dynamics Study of Quadrupolar Spin Relaxation in an Ionic Liquid
This study presents a methodology for describing the relaxation of nuclear spins (with I > 1/2), applicable to ionic liquids of a general nature. Based on ab initio molecular dynamics, we demonstrate the importance of explicit solvation in calculating the relaxation times of the quadrupolar mechanism.
Luciano N. Vidal +2 more
wiley +1 more source
Superstructure-induced enhancement of solid-state triphenylacrylonitrile photochromism via a macrocycle-mediated blocking strategy. [PDF]
Li MH, Hui H, Wang Y, Yang YW.
europepmc +1 more source
Development and Validation of High-Performance Thin Layer Chromatographic Method for the Simultaneous Estimation of Dapagliflozin and Vildagliptin in Fixed-Dose Combination. [PDF]
Krishnamoorthy YV +2 more
europepmc +1 more source
Thiophene Derivatives as Versatile Precursors for (Hetero)Arene and Natural Product Synthesis
Hidden but Powerful: Thiophenes and their saturated analogues have been demonstrated to be versatile C4‐building blocks that can be rapidly applied to natural product synthesis and the construction of functionalized (hetero)arenes. This minireview aims to provide a concise overview of the strategies and implementations of these sulfur‐containing ...
Anna Keimer, Franz‐Lucas Haut
wiley +1 more source
Compositions, Antimicrobial, and Antioxidant Activities of the Essential Oil Extracted From Garden Cress Seeds Growing in Three Districts of South Wollo, Ethiopia. [PDF]
Asfaw MD, Awoke MG, Yadeta AT.
europepmc +1 more source

