Results 1 to 10 of about 565 (139)

One-pot H/D exchange and low-coordinated iron electrocatalyzed deuteration of nitriles in D2O to α,β-deuterio aryl ethylamines [PDF]

open access: yesNature Communications, 2022
One-pot efficient synthesis of α,β-deuterio aryl ethylamines with high deuterium ratios using an easy-to-handle deuterated source under ambient conditions is desirable.
Rui Li   +5 more
doaj   +2 more sources

Reductive Methylation of Homogeneous Primary β-Lauryl/myristyl 7/3 Polyethyleneoxy n = 3–18 Ethylamines under Phase-Transfer Catalysis Conditions [PDF]

open access: yesMolecules, 2021
Homogeneous tertiary N,N-dimethyl-N-β-lauryl/myristyl 7/3 polyethyleneoxy n = 3–18 ethylamines, LM(EO)nAT, are niche intermediates in the synthesis of homogeneous N-alkyl (C1–C18)-N,N-dimethyl-N-β-lauryl/myristyl 7/3 polyethyleneoxy n = 3–18 ...
Călin Jianu
doaj   +2 more sources

Electrochemical reduction of acetonitrile to ethylamine [PDF]

open access: yesNature Communications, 2021
AbstractElectrifying chemical manufacturing using renewable energy is an attractive approach to reduce the dependence on fossil energy sources in chemical industries. Primary amines are important organic building blocks; however, the synthesis is often hindered by the poor selectivity because of the formation of secondary and tertiary amine byproducts.
Rong Xia   +7 more
openaire   +4 more sources

Synthesis of dichloroacetamides and study of their anti-tumor activity

open access: yesФармацевтичний журнал, 2022
Dichloroacetic acid and its derivatives exhibit the properties of metabolic cytoprotectors and apoptosis inducers. Nowadays evaluation of these derivatives is being conducted regarding the induction of immunogenic cell death.
L. M. Havryshchuk   +2 more
doaj   +1 more source

Parallel Synthesis of 2-Substituted 6-(5-Oxo-1-phenylpyrrolidin-3-yl)pyrimidine-5-carboxamides

open access: yesMolecules, 2012
A library of 24 6-(5-oxo-1-phenylpyrrolidin-3-yl)pyrimidine-5-carboxamides <strong>10</strong>{<em>1</em>,<em>2</em>; <em>1–12</em>} was prepared by a parallel solution-phase approach.
Branko Stanovnik   +6 more
doaj   +1 more source

Viral Infection‐Inspired Autonomous Detection of Fusion‐Competent Viruses for Screening and Environmental Surveillance

open access: yesAdvanced Materials, EarlyView.
Inspired by viral entry mechanisms, the FUSION assay enables autonomous detection of respiratory viruses via membrane fusion–triggered CRISPR‐Cas13a activation. VEACON selectively fuses with fusion‐competent viruses, triggering fluorescence within confined vesicles.
Jae Chul Park   +15 more
wiley   +1 more source

Smart Exploration of Perovskite Photovoltaics: From AI Driven Discovery to Autonomous Laboratories

open access: yesAdvanced Energy Materials, EarlyView.
In this review, we summarize the fundamentals of AI in automated materials science, and review AI applications in perovskite solar cells. Then, we sum up recent progress in AI‐guided manufacturing optimization, and highlight AI‐driven high‐throughput and autonomous laboratories.
Wenning Chen   +4 more
wiley   +1 more source

Constructing Enzyme‐Inspired Multisite Synergistic Catalyst for Promoting CO2 Electroreduction to Ethylene at pH Universal Condition

open access: yesCarbon Energy, EarlyView.
A rational synthesis strategy was developed to construct enzyme‐inspired Cu‐AM catalysts with well‐defined multisite architectures. This catalytic system enables highly selective electrochemical CO2 reduction to C2H4 under pH‐universal conditions, delivering exceptional Faradaic efficiencies across acidic, neutral, and alkaline electrolytes.
Yahui Wu   +4 more
wiley   +1 more source

III. On the preparation of ethylamine [PDF]

open access: yesProceedings of the Royal Society of London
Abstract Having recently had occasion to prepare a considerable quantity of ethylamine, we have made the observation that this base may be obtained with much greater facility than is usually believed. We digested together equal volumes of iodide of ethyl, strong alcohol, and aqueous ammonia.
J. Alfred Wanklyn, Ernest T. Chapman
openaire   +1 more source

Pd(II)‐Catalyzed Strategies for the β‐Arylation of α‐Amino Acids: An Overview

open access: yesChemistry – A European Journal, EarlyView.
The graphical abstract summarizes the review “Pd(II)‐Catalyzed Strategies for the β‐Arylation of α‐Amino Acids: An Overview”, highlighting representative Pd(II)‐catalyzed methods for the β‐arylation of α‐amino acids. Key mechanistic features, substrate diversity, and synthetic relevance of these transformations are showcased. Abstract Metal‐catalyzed C─
Davide Illuminati   +4 more
wiley   +1 more source

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