Results 11 to 20 of about 725,129 (303)

Synthesis of difluoromethylated allenes through trifunctionalization of 1,3-enynes

open access: yesNature Communications, 2020
Fluorinated or fluoroalkylated allenes are versatile building blocks for medicinal and material chemistry. Here, the authors show a regioselective trifunctionalization of 1,3-enynes proceeding through double C-F bond formation and concomitant ...
Munira Taj Muhammad   +9 more
doaj   +1 more source

Asymmetric radical carboesterification of dienes

open access: yesNature Communications, 2021
Stereocontrol of C–O bond formation from a carbon-based radical is very difficult due to the rapid inversion of the carbon radical. Here the authors present a method to form chiral esters from conjugated dienes with copper and chiral PyBox ligands ...
Xiaotao Zhu   +6 more
doaj   +1 more source

Climacteric fruit ripening: Ethylene-dependent and independent regulation of ripening pathways in melon fruit [PDF]

open access: yes, 2008
Cantaloupe melons have a typical climacteric behaviour with ethylene playing a major role in the regulation of the ripening process and affecting the ripening rate.
A. Latché   +57 more
core   +2 more sources

Influence of ethylene oxide gas treatment on the in vitro degradation behavior of dermal sheep collagen [PDF]

open access: yes, 1995
The influence of ethylene oxide gas treatment on the in vitro degradation behavior of noncrosslinked, glutaraldehyde crosslinked or hexamethylene diisocyanate crosslinked dermal sheep collagen (DSC) using bacterial collagenase is described.
Dijkstra, P.J.   +5 more
core   +12 more sources

Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift

open access: yesNature Communications, 2020
Transannular construction of medium-sized lactones is entropically unfavoured. Herein, the authors describe a strategy for valuable medium-sized lactone synthesis from available benzaldehydes by selective C-H bond functionalization via palladium carbene ...
Yinghua Yu   +5 more
doaj   +1 more source

Revealing the Iron-Catalyzed β-Methyl Scission of tert-Butoxyl Radicals via the Mechanistic Studies of Carboazidation of Alkenes

open access: yesMolecules, 2020
We describe here a mechanistic study of the iron-catalyzed carboazidation of alkenes involving an intriguing metal-assisted β-methyl scission process.
Mong-Feng Chiou   +4 more
doaj   +1 more source

Role of ethylene on various ripening pathways and on the development of sensory quality of Charentais cantaloupe melons [PDF]

open access: yes, 2002
Charentais melons (Cucumis melo L., var cantalupensis Naud.) in which ethylene biosynthesis has been suppressed by an antisense ACC oxidase gene have been used to better understand the role of ethylene in the regulation of the ripening process of ...
Ambid, Christian   +9 more
core   +1 more source

Focus on Ethylene [PDF]

open access: yesPlant Physiology, 2015
First discovered as a plant growth regulator over a century ago, ethylene continues to be a focus for research worldwide due to the many roles it plays in growth, development, and adaptive responses to biotic and abiotic factors.
Eric Schaller, G.   +1 more
openaire   +4 more sources

A dominant repressor version of the tomatoSl-ERF.B3gene confers ethylene hypersensitivity via feedback regulation of ethylene signaling and response components [PDF]

open access: yes, 2013
Ethylene Response Factors (ERFs) are downstream components of the ethylene signal transduction pathway, although their role in ethylene-dependent developmental processes remains poorly understood. As the ethylene-inducible tomato Sl-ERF.B3 has been shown
Achard   +51 more
core   +4 more sources

Tissue specific analysis reveals a differential organization and regulation of both ethylene biosynthesis and E8 during climacteric ripening of tomato [PDF]

open access: yes, 2014
Background: Solanum lycopersicum or tomato is extensively studied with respect to the ethylene metabolism during climacteric ripening, focusing almost exclusively on fruit pericarp. In this work the ethylene biosynthesis pathway was examined in all major
Bulens, Inge   +14 more
core   +2 more sources

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