Radical azidation as a means of constructing C(sp3)-N3 bonds
The azido group is found in large numbers of natural products, drugs, biochemicals and materials and to date, many elegant and useful methods for the synthesis of organic azides and their transformations have been documented. In this review, we provide a
Liang Ge +3 more
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Radical Decarboxylative Carbon–Nitrogen Bond Formation
The carbon–nitrogen bond is one of the most prevalent chemical bonds in natural and artificial molecules, as many naturally existing organic molecules, pharmaceuticals, agrochemicals, and functional materials contain at least one nitrogen atom.
Xiangting Li +4 more
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Ethylene signalling receptors and transcription factors over the grape berry development: gene expression profiling [PDF]
The ethylene signalling pathway has never been fully described in grapes. Regarded as a non-climacteric fruit, grape berry seems to ripen independently to ethylene, however 1-methylcyclopropene (1-MCP), a specific inhibitor of ethylene receptors has been
Chervin, Christian +4 more
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Transannular construction of medium-sized lactones is entropically unfavoured. Herein, the authors describe a strategy for valuable medium-sized lactone synthesis from available benzaldehydes by selective C-H bond functionalization via palladium carbene ...
Yinghua Yu +5 more
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We describe here a mechanistic study of the iron-catalyzed carboazidation of alkenes involving an intriguing metal-assisted β-methyl scission process.
Mong-Feng Chiou +4 more
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Asymmetric radical carboesterification of dienes
Stereocontrol of C–O bond formation from a carbon-based radical is very difficult due to the rapid inversion of the carbon radical. Here the authors present a method to form chiral esters from conjugated dienes with copper and chiral PyBox ligands ...
Xiaotao Zhu +6 more
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Climacteric fruit ripening: Ethylene-dependent and independent regulation of ripening pathways in melon fruit [PDF]
Cantaloupe melons have a typical climacteric behaviour with ethylene playing a major role in the regulation of the ripening process and affecting the ripening rate.
Latché, Alain +5 more
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A conserved phosphorylation site regulates the transcriptional function of ETHYLENE-INSENSITIVE3-like1 in tomato [PDF]
ETHYLENE-INSENSITIVE3/ETHYLENE-INSENSITIVE3-like (EIN3/EIL) transcription factors are important downstream components of the ethylene transduction pathway known to regulate the transcription of early ethylene-responsive genes in plants.
Z. Li +11 more
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Regeneration and Reuse of Activated Carbon for Dye Adsorption under Ambient Conditions Using Dilute Chemical Solutions [PDF]
This study investigated the regeneration and reuse of methylene blue-loaded activated carbon using dilute 0.1 M hydrochloric acid (HCl) and sodium hydroxide (NaOH) under ambient conditions. Batch adsorption experiments were conducted at initial methylene
Rosli Muhammad Alif Basyar +2 more
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Ethylene and 1-methylcyclopropene differentially regulate gene expression during onion sprout suppression. [PDF]
Onion (Allium cepa) is regarded as a nonclimacteric vegetable. In onions, however, ethylene can suppress sprouting while the ethylene-binding inhibitor 1- methylcyclopropene (1-MCP) can also suppress sprout growth; yet, it is unknown how ethylene and ...
Thompson, Andrew J. +11 more
core +1 more source

