Results 21 to 30 of about 831,442 (355)

Asymmetric radical carboesterification of dienes

open access: yesNature Communications, 2021
Stereocontrol of C–O bond formation from a carbon-based radical is very difficult due to the rapid inversion of the carbon radical. Here the authors present a method to form chiral esters from conjugated dienes with copper and chiral PyBox ligands ...
Xiaotao Zhu   +6 more
doaj   +1 more source

Role of ethylene on various ripening pathways and on the development of sensory quality of Charentais cantaloupe melons [PDF]

open access: yes, 2002
Charentais melons (Cucumis melo L., var cantalupensis Naud.) in which ethylene biosynthesis has been suppressed by an antisense ACC oxidase gene have been used to better understand the role of ethylene in the regulation of the ripening process of ...
Ambid, Christian   +9 more
core   +1 more source

Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift

open access: yesNature Communications, 2020
Transannular construction of medium-sized lactones is entropically unfavoured. Herein, the authors describe a strategy for valuable medium-sized lactone synthesis from available benzaldehydes by selective C-H bond functionalization via palladium carbene ...
Yinghua Yu   +5 more
doaj   +1 more source

Revealing the Iron-Catalyzed β-Methyl Scission of tert-Butoxyl Radicals via the Mechanistic Studies of Carboazidation of Alkenes

open access: yesMolecules, 2020
We describe here a mechanistic study of the iron-catalyzed carboazidation of alkenes involving an intriguing metal-assisted β-methyl scission process.
Mong-Feng Chiou   +4 more
doaj   +1 more source

Focus on Ethylene [PDF]

open access: yesPlant Physiology, 2015
First discovered as a plant growth regulator over a century ago, ethylene continues to be a focus for research worldwide due to the many roles it plays in growth, development, and adaptive responses to biotic and abiotic factors.
Eric Schaller, G.   +1 more
openaire   +4 more sources

Cadmium-induced ethylene production and responses in Arabidopsis thaliana rely on ACS2 and ACS6 gene expression [PDF]

open access: yes, 2014
Background: Anthropogenic activities cause metal pollution worldwide. Plants can absorb and accumulate these metals through their root system, inducing stress as a result of excess metal concentrations inside the plant.
Cuypers, Ann   +6 more
core   +3 more sources

The Introduction of the Radical Cascade Reaction into Polymer Chemistry: A One-Step Strategy for Synchronized Polymerization and Modification

open access: yesiScience, 2020
Summary: Polymerization and modification play central roles in polymer chemistry and are generally implemented in two steps, which suffer from the time-consuming two-step strategy and present considerable challenge for complete modification.
Nengbo Zhu   +7 more
doaj   +1 more source

A dominant repressor version of the tomatoSl-ERF.B3gene confers ethylene hypersensitivity via feedback regulation of ethylene signaling and response components [PDF]

open access: yes, 2013
Ethylene Response Factors (ERFs) are downstream components of the ethylene signal transduction pathway, although their role in ethylene-dependent developmental processes remains poorly understood. As the ethylene-inducible tomato Sl-ERF.B3 has been shown
Achard   +51 more
core   +4 more sources

ER5, a tomato cDNA encoding an ethylene-responsive LEA-like protein: characterization and expression in response to drought, ABA and wounding [PDF]

open access: yes, 1997
We report the isolation by differential display of a novel tomato ethylene-responsive cDNA, designated ER5. RT-PCR analysis of ER5 expression revealed an early (15 min) and transient induction by ethylene in tomato fruit, leaves and roots.
Bouzayen, Mondher   +6 more
core   +2 more sources

Effects of chilling on the expression of ethylene biosynthetic genes in Passe-Crassane pear (Pyrus communis L.) fruits [PDF]

open access: yes, 1997
Passe-Crassane pears require a 3-month chilling treatment at 0 C to be able to produce ethylene and ripen autonomously after subsequent rewarming. The chilling treatment strongly stimulated ACC oxidase activity, and to a lesser extent ACC synthase ...
Dao, Patrick   +6 more
core   +2 more sources

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