Results 11 to 20 of about 166,653 (305)

Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift

Nature Communications, 2020
Transannular construction of medium-sized lactones is entropically unfavoured. Herein, the authors describe a strategy for valuable medium-sized lactone synthesis from available benzaldehydes by selective C-H bond functionalization via palladium carbene ...
Yinghua Yu, Pushkin Chakraborty, Jinshuai Song, Lei Zhu, Chunsen Li, Xueliang Huang   +5 more
doaj   +1 more source

Radical azidation as a means of constructing C(sp3)-N3 bonds

Green Synthesis and Catalysis, 2020
The azido group is found in large numbers of natural products, drugs, biochemicals and materials and to date, many elegant and useful methods for the synthesis of organic azides and their transformations have been documented. In this review, we provide a
Liang Ge, Mong-Feng Chiou, Yajun Li, Hongli Bao   +3 more
doaj   +1 more source

Synthesis of difluoromethylated allenes through trifunctionalization of 1,3-enynes

Nature Communications, 2020
Fluorinated or fluoroalkylated allenes are versatile building blocks for medicinal and material chemistry. Here, the authors show a regioselective trifunctionalization of 1,3-enynes proceeding through double C-F bond formation and concomitant ...
Munira Taj Muhammad, Yihang Jiao, Changqing Ye, Mong-Feng Chiou, Muhammad Israr, Xiaotao Zhu, Yajun Li, Zhenhai Wen, Armido Studer, Hongli Bao   +9 more
doaj   +1 more source

Revealing the Iron-Catalyzed β-Methyl Scission of tert-Butoxyl Radicals via the Mechanistic Studies of Carboazidation of Alkenes

Molecules, 2020
We describe here a mechanistic study of the iron-catalyzed carboazidation of alkenes involving an intriguing metal-assisted β-methyl scission process.
Mong-Feng Chiou, Haigen Xiong, Yajun Li, Hongli Bao, Xinhao Zhang   +4 more
doaj   +1 more source

The Introduction of the Radical Cascade Reaction into Polymer Chemistry: A One-Step Strategy for Synchronized Polymerization and Modification

iScience, 2020
Summary: Polymerization and modification play central roles in polymer chemistry and are generally implemented in two steps, which suffer from the time-consuming two-step strategy and present considerable challenge for complete modification.
Nengbo Zhu, Mong-Feng Chiou, Haigen Xiong, Min Su, Muqiao Su, Yajun Li, Wen-Ming Wan, Hongli Bao   +7 more
doaj   +1 more source

Ag-doped Pd nano-dendritic for promoting the electrocatalytic oxidation of ethylene to ethylene glycol

, 2023
Ethylene glycol is the core chemical stock for the manufacture of polyester and antifreeze that consumes around 20 million tonnes per year. Current industrial production suffers from large energy consumption, complicated operation, and high pollution ...
Yang, C, Lu, S, You, X, Huang, X, Li, X, Yan, Z, Chang, L, Zuo, L, Tang, Z   +8 more
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Boron Modified Bifunctional Cu/SiO₂ Catalysts with Enhanced Metal Dispersion and Surface Acid Sites for Selective Hydrogenation of Dimethyl Oxalate to Ethylene Glycol and Ethanol

Nanomaterials, 2021
Boron (B) promoter modified Cu/SiO2 bifunctional catalysts were synthesized by sol-gel method and used to produce ethylene glycol (EG) and ethanol (EtOH) through efficient hydrogenation of dimethyl oxalate (DMO).
Deliang Yang, Runping Ye, Ling Lin, Rong Guo, Peiyu Zhao, Yanchao Yin, Wei Cheng, Wenpeng Yuan, Yuangen Yao   +8 more
doaj   +1 more source

Corrosion Behavior of ZrCrMoNb High-entropy Alloy Coating in Ethylene Glycol Solution

International Journal of Electrochemical Science, 2021
A novel ZrCrMoNb high-entropy alloy coating was prepared on 3A21 aluminum alloy and its corrosion behavior in ethylene glycol solution was studied. By polarization curve, electrochemical impedance spectroscopy (EIS) and scanning electron microscope (SEM),
Hanyang Zuo, Long Wang, Min Gong, Xingwen Zheng, Chunhai Liu, Jinlong Fan, Feng Liu   +6 more
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ETHYLENE GLYCOL POISONING WITH CONCURRENT ETHANOL INGESTION

Zdravniški Vestnik, 2003
Background. Ethylene glycol, usually ingested by coincidence, causes uncommon but serious poisoning which could have fatal consequences without prompt diagnosis and treatment.
Mitja Lainščak, Vlasta Petric, Rudolf Mikolič, Franc Štivan   +3 more
doaj   +2 more sources

Corrosion Behavior of 3A21 Aluminum Alloy in Water-Ethylene Glycol Coolant under Simulated Engine Working Conditions

International Journal of Electrochemical Science, 2021
In this work, the corrosion behavior of 3A21 aluminum alloy in ethylene glycol coolant was studied under simulated working conditions of automotive engine.
Hanyang Zuo, Jinlong Fan, Feng Liu, Min Gong, Xingwen Zheng, Junchen Meng, Guangming Yang, Xiaohua Liu   +7 more
doaj   +1 more source