Phase Engineering of Nanomaterials (PEN): Evolution, Current Challenges, and Future Opportunities
Advanced Materials, EarlyView.This review summarizes the synthesis, phase transition, advanced characterization spanning ex situ to in situ and operando techniques, and diverse applications of phase engineering of nanomaterials (PEN). It further outlines key challenges and future opportunities, such as phase stability, architecture control, and artificial intelligence (AI)‐driven ...
Ye Chen +7 more
wiley +1 more source
Influence of Metal-Alkyls on Early-Stage Ethylene Polymerization over a Cr/SiO2 Phillips Catalyst: A Bulk Characterization and X-ray Chemical Imaging Study. [PDF]
Chemistry, 2021 Jongkind MK +8 more
europepmc +1 more source
Additive Manufacturing of Ordered Polymer Nanostructures
Advanced Materials, EarlyView.A new 3D printing strategy, Polymerization‐Induced Arrangement of Nanostructures with Order‐tunability (PIANO), enables the formation of ordered nanostructures in polymer materials by enhancing chain mobility during photopolymerization, overcoming the kinetic arrest that leads to disordered morphologies in the conventional Polymerization‐Induced ...
Di Wu +6 more
wiley +1 more source
Lead Halide Perovskite Photoelectrocatalysis
Advanced Materials, EarlyView.Lead halide perovskite semiconductors have emerged as highly promising materials for solar fuel and chemical synthesis. This perspective discusses advances made in the rational photoelectrode design to improve solar‐to‐chemical conversion, product scope, and scalability.
Virgil Andrei
wiley +1 more source
High molecular weight PE elastomers through 4,4-difluorobenzhydryl substitution in symmetrical α-diimino-nickel ethylene polymerization catalysts. [PDF]
RSC Adv, 2022 Zheng Y +8 more
europepmc +1 more source
Highly Entangled Bottlebrush Polymer Networks
Advanced Materials, EarlyView.Bottlebrush polymers are difficult to entangle, enabling ultrasoft yet brittle networks. We report highly entangled bottlebrush elastomers that remain ultrasoft (∼1 kPa) yet stretch to ∼1800% and exhibit exceptional fatigue resistance. Their intrinsic fatigue strength—fatigue threshold normalized by modulus—surpasses that of highly entangled linear ...
Myoeum Kim +3 more
wiley +1 more source
Modelling the Load Torques of Electric Drive for Polymerization Process
Advances in Electrical and Electronic Engineering, 2007 The problems of mathematical modelling the load torques on shaft of driving motor designed for applications in polymerization reactors are presented in the paper.
Andrzej Popenda
doaj
Advanced Materials, EarlyView.A sustainable δ‐lactone‐based polymer platform enables multimodal additive manufacturing through DLP, DIW, and FFF, combining tunable crystallinity, photocurable networks, mechanical robustness, and functional response. The printed materials can be mechanically reprocessed and chemically depolymerized into recoverable monomers, demonstrating a closed ...
Farzad Gholami +2 more
wiley +1 more source
Uranium(iv) alkyl cations: synthesis, structures, comparison with thorium(iv) analogues, and the influence of arene-coordination on thermal stability and ethylene polymerization activity. [PDF]
Chem Sci, 2022 Andreychuk NR +13 more
europepmc +1 more source
Stabilized Bi(III) Sites Direct *NH2OH Pathway for Efficient Cyclohexanone Oxime Electrosynthesis
Advanced Materials, EarlyView.The electron‐buffering effect stabilizes Bi3+ sites under electroreductive conditions, preserving a favorable interfacial water configuration that sustains the selective *NH2OH pathway and enables efficient cyclohexanone oxime electrosynthesis. ABSTRACT Coupling electrocatalytic nitrite reduction reaction (NO2−RR) with cyclohexanone conversion enables ...
Zichao Xi +8 more
wiley +1 more source