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Zirconium complexes in homogeneous ethylene polymerization
Journal of Coordination Chemistry, 2011This article reviews the recent progress of zirconium complexes for ethylene polymerization. Zirconium complexes are one of the most important types of catalysts for homogeneous ethylene polymerization. Polymerization behavior and polymer structure can be adjusted through the balancing of ligand structure.
Ataf Ali Altaf +4 more
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Emulsion polymerization of ethylene. I. Polymerization formulas and conditions
Journal of Applied Polymer Science, 1965Formulas and operating conditions for the emulsion polymerization of ethylene are described. Stable latex products were obtained with a variety of anionic and nonionic emulsifiers, but for the majority of the work fatty acids or polyethoxylated alkyl phenols were used.
Arthur F. Helin +2 more
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Titanium-biphenoxide catalysts for ethylene polymerization
Journal of Polymer Research, 2012Titanium (IV) complexes containing sterically bulky ligands such as 2, 2′- methylenebis (4-methyl-6-tert butyl phenol) (MBTP) were synthesized by stoichiometric reaction between Ti(IV)alkoxide or halide and the biphenol. These catalyst precursors formulated as [Ti(O^O)RR′] were characterized by physicochemical and spectroscopic methods.
Akshay Mehta +5 more
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Promoting ethylene polymerization through cocatalyst modification
Polymer Bulletin, 2015Effect of chlorocyclohexane (CHC) on ethylene polymerization using MgCl2/TiCl4/TEA Ziegler–Natta catalyst system was studied, where MgCl2, TiCl4, and TEA (triethyl aluminum) were used as support, catalyst, and activator, respectively. The polymerization rate, catalyst activity, and produced polymer were significantly affected by the presence of CHC as
Sadegh Abedi +4 more
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Substituted chromocenes for ethylene polymerization catalysts
Journal of Molecular Catalysis, 1991Abstract Four different chromocenes, in which two hydrogen atoms in the 1 and 1' positions have been substituted by ethyl, t-butyl, trimethylsilyl and phenyl groups, have been reacted with silica gel. As in the case with chromocene (IR bands of adsorbed CO at 2047.1, 1972.2, 1917.2, 1824.1 and 1621.4 cm−1) five strong CO bands are observed, of which ...
B. Rebenstorf, C. Panda
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Polymerization of ethylene glycol dimethacrylate
Journal of Polymer Science, 1959AbstractIn the polymerization of ethylene glycol dimethacrylate (EDMA), the content of pendant double bonds (PDB) in the polymer was found to be lower than expected, hence it was deduced that the intramolecular cyclizations occurred in the polymerization.
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ETHYLENE POLYMERIZATION USING THE PHILLIPS CATALYST
2023The Phillips catalyst, chromate on silica support, is widely used to manufacture polyethylene. It is activated in an oxygen-rich environment before conducting polymerization. The polymerization involves an initial period of inactivity called the induction period, during which active site formation occurs, and ethylene acts as a reductant. To avoid this
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Rate of Ethylene Polymerization
Industrial & Engineering Chemistry, 1938F. R. Russell, H. C. Hottel
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Organometallics in Ethylene Polymerization
Industrial & Engineering Chemistry, 1957H. N. Friedlander, Katashi. Oita
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