Results 61 to 70 of about 115,445 (306)

Synthesis of Early Transition Metal Bisphenolate Complexes and Their Use as Olefin Polymerization Catalysts [PDF]

, 2009
Bisphenolate ligands with pyridine- and benzene-diyl linkers have been synthesized and metalated with group 4 and 5 transition metals. The solid-state structures of some of the group 4 complexes have been solved.
Bercaw, John E., Golisz, Suzanne R.
core   +1 more source

Hybrid materials based on polyethylene and MCM-41 microparticles functionalized with silanes: catalytic aspects of in situ polymerization, crystalline features and mechanical properties [PDF]

, 2016
New nanocomposites based on polyethylene have been prepared by in situ polymerization of ethylene in presence of mesoporous MCM-41. The polymerization reactions were performed using a zirconocene catalyst either under homogenous conditions or supported
A. Bento, Alexander, Alonso-Moreno, Arranz-Andrés, Arranz-Andrés, Arranz-Andrés, Beck, Bento, Boyd, Bunn, Campos, Campos, Cerrada, Cerrada, Cerrada, Cerrada, Cerrada, Cerrada, Cerrada, Cerrada, Chen, Chen, Chenite, Darras, Diez-Pascual, dos Santos, E. Pérez, Finch, Fonseca, Fox, Gedde, Ha, Heijboer, Hiltner, J.P. Lourenço, Jafari, Jentys, Jezequel, Kageyama, Kageyama, Kubacka, Kubacka, Lin, Lourenco, Lu, López-Majada, M.L. Cerrada, M.R. Ribeiro, Marcilla, McCrum, Millot, Oliver, Palza, Palza, Popli, Popli, Prieto, Quinn, Schatzki, Shin, Shirayam, Sindorf, Sinfrônio, V. Lorenzo, Vincent, Ward, Wunderlich, Wunderlich, Ye, Zapata, Zhao   +70 more
core   +1 more source

Synthesis of a Novel Thermoresponsive S53P4 Bioactive Glass Extract–Poloxamer 407 Injectable Hydrogels: Assessment of Biocompatibility and Antimicrobial Properties

Advanced Engineering Materials, EarlyView.
This study investigates innovative thermoreversible hydrogels derived from S53P4 bioactive glass extracts to aid in the healing of infected diabetic foot wounds. These injectable gels, which gel at body temperature, release beneficial ions and remain stable over time.
Marian G. Vargas Guerrero, Adrian Stiller, Alex Nygård, Matej Krivulka, Lars Galema, Erwin Peters, Jimmy Lucchesi, Peter Uppstu, Leena Hupa, Jacobus J. C. Arts   +9 more
wiley   +1 more source

Polymerization of Ethylene by the Silaned SiO2 -Mg(iBu)2-TiCl4-Al(iBu)3 Catalyst System [PDF]

مجلة جامعة النجاح للأبحاث العلوم الطبيعية, 1992
The polymerization of ethylene was conducted over the Silaned Si02 / Mg(iBu)2 I TiCl I Al (mu)3 and over the Stauffer AA type (1.1)/Al (iBu)3 catalyst systems at 60° C.
M.A. Abu-Eid, P.J. Tait
doaj   +1 more source

Ethylene Copolymerization with Linear and End-Cyclized Olefins via a Metallocene Catalyst: Polymerization Behavior and Thermal Properties of Copolymers

Engineering, 2023
Olefin solution polymerization can be used to obtain high-performance polyolefin materials that cannot be obtained via other polymerization processes. Polyolefin elastomers (POE) are a typical example.
Changjiang Wu, Minqiao Ren, Liping Hou, Shuzhang Qu, Xinwei Li, Cui Zheng, Jian Chen, Wei Wang   +7 more
doaj   +1 more source

ORGANOMETALLIC CATALYSTS FOR ETHYLENE POLYMERIZATION

Messenger AmSU, 2021
The use of organometallic catalysts in ethylene polymerization at low pressure is considered. A comparative characteristic of different generations of catalysts and their influence on the physical and mechanical properties of polymers is given.
openaire   +1 more source

Sol–Gel Derived Polymer Precursors for Stereolithography of ZrC

Advanced Engineering Materials, EarlyView.
ZrC is a critical material target for extreme temperature conditions. This report describes a protocol for preparing ZrC ceramics via stereolithography and examines the impact of the polymer matrix on carbothermal reduction and mechanical stability of 3D printed ZrC.
Charles J. Rafalko, Evelyn Wang, Michael A. Hickner   +2 more
wiley   +1 more source

Periodic current oscillations of zinc in nitric acid solutions [PDF]

Journal of the Serbian Chemical Society, 2008
The charge percolation mechanism (CPM) of olefin polymerization in the presence of transition metal compounds has been applied to explain the polymerization of ethylene by silica supported chromium oxide.
ERVIN SALLÓ, FLORIN CRISAN
doaj  

Molecular weight control in organochromium olefin polymerization catalysis by hemilabile ligand–metal interactions

Beilstein Journal of Organic Chemistry, 2016
A series of Cr(III) complexes based on quinoline-cyclopentadienyl ligands with additional hemilabile side arms were prepared and used as single-site catalyst precursors for ethylene polymerization.
Stefan Mark, Hubert Wadepohl, Markus Enders   +2 more
doaj   +1 more source

Understanding and Optimizing Li Substitution in P2‐Type Sodium Layered Oxides for Sodium‐Ion Batteries

Advanced Functional Materials, EarlyView.
This work explores Li‐substituted P2 layered oxides for Na‐ion batteries by crystallographic and electrochemical studies. The effect of lithium on superstructure orderings, on phase transitions during synthesis and electrochemical cycling and on the interplay of O‐ versus TM‐redox is revealed via various advanced techniques, including semi‐simultaneous 
Mingfeng Xu, Giovanni Gammaitoni, Michael Häfner, Eduardo Villalobos‐Portillo, Carlo Marini, Matteo Bianchini   +5 more
wiley   +1 more source