Results 171 to 180 of about 44,774 (227)

Orbital‐Selective Modulation of Spatial pz‐s Hybridization for Enhanced Photocatalytic H2 Evolution: Insights From NiSe@ReS2+x Cocatalyst

open access: yesAngewandte Chemie, EarlyView.
Spatial orbital‐selective modulation engineering is proposed as a strategy to optimize cocatalyst design, enhance photocatalytic activity, and provide novel insights into the interactions between active sites and adsorbates, as well as catalytic mechanisms.
Duoduo Gao   +5 more
wiley   +2 more sources

Atomically Dispersed Cobalt on Ionic Carbon Nitrides for Selective and Efficient Nitrate Electroreduction to Ammonia

open access: yesAngewandte Chemie, EarlyView.
By exploiting the structural benefits of PHI, we synthesized CoPHI with atomically dispersed cobalt sites at high density. This architecture enables efficient nitrate ion adsorption, promotes water dissociation, and enhances *H generation on the catalyst surface, thereby significantly improving electrochemical nitrate reduction performance.
Nana Gao   +14 more
wiley   +2 more sources

Reversible temperature-induced shape transition of Pt nanoparticles supported on Al<sub>2</sub>O<sub>3</sub>. [PDF]

open access: yesNanoscale Adv
Pool Mazun R   +10 more
europepmc   +1 more source

Upcycling Spent Lithium Iron Phosphate Battery Into Fe‐CN3P Single Atom Catalyst for Environmental Remediation

open access: yesAngewandte Chemie, EarlyView.
Electrochemical (EC) advanced oxidation enables near‐complete lithium and iron recovery from spent lithium iron phosphate batteries, while simultaneously transforming leach residues into a high‐performance P, N‐doped single‐atom Fe catalyst. The reconstructed Fe–CN3P catalyst exhibits exceptional peroxymonosulfate (PMS) activation and rapid bisphenol A
Xianhui Ke   +6 more
wiley   +2 more sources

Atomic-scale structure of gadolinium in nanocrystalline fluorapatite from marine sediments.

open access: yesEnviron Sci Nano
Manceau A   +9 more
europepmc   +1 more source

Heterophase fcc-hcp-fcc High-Entropy Alloy Nanomaterials with Tailored Electron Divergence for Selective Ammonia Electrosynthesis. [PDF]

open access: yesAdv Mater
Meng X   +18 more
europepmc   +1 more source

Ligand‐Intercalated MOFs Enable Reaction‐Pathway Engineering in Biomass Electrooxidation via Steric and π‐Electronic Microenvironment Control

open access: yesAngewandte Chemie, EarlyView.
Through ligand length and π‐electron density modulation, metal–organic frameworks (MOFs) improve mass transport and hydrogen atom transfer (HAT), thus improving biomass electrooxidation. ABSTRACT Controlling reaction pathways in electrocatalytic biomass upgrading remains challenging because mass transport, substrate adsorption, and elementary kinetics ...
Junjie Chen   +12 more
wiley   +2 more sources

Structural Evidence of Interanionic Hydrogen Bonding in Phosphoric Acid Solutions. [PDF]

open access: yesJ Am Chem Soc
Kim P   +5 more
europepmc   +1 more source

Harnessing Support‐Dependent Hydrogen Spillover for Ni‐Based CO2 Hydrogenation

open access: yesAngewandte Chemie, EarlyView.
Hydrogen spillover can be harnessed for Ni‐based CO2 hydrogenation via support‐dependent pathways. Hydrogen spillover propagating to surfaces promotes catalysis through two distinct mechanisms. On moderately reducible supports, it rapidly removes poisoning oxygen species (*O) from Ni nanoparticles.
Kazuki Shun   +3 more
wiley   +2 more sources

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