Results 31 to 40 of about 484 (218)

Ultrafast Thermal Shock Synthesis of CuNiSnLa Medium‐Entropy Metallic Glass for Sustainable Nitrogen Fixation via Plasma‐Coupled Electrocatalysis

open access: yesAdvanced Functional Materials, EarlyView.
This work introduces an ultrafast thermal shock strategy to synthesize a CuNiSnLa medium‐entropy metallic glass (MEMG). The rapid heating and cooling process generates a robust, highly active catalyst for electrocatalytic nitrate reduction to ammonia (NRA).
Hongbo Chen   +7 more
wiley   +1 more source

STRUCTURAL STUDY OF BIS(2,6-BIS(PYRAZOL-3-YL)PYRIDINE)NICKEL(II) BY CALORIMETRY AND EXAFS SPECTROMETRY

open access: yesIndonesian Journal of Chemistry, 2010
The main aim of this work is to reveal the complex formation of 2,6-bis(pyrazol-3-yl)pyridine, bpp, with nickel(II) perchlorate in DMF by calorimetric stepwise complex formation and then followed by EXAFS spectrometry.
Kristian H Sugiyarto
doaj   +1 more source

Extended X-ray absorption fine structure spectroscopy measurements and ab initio molecular dynamics simulations reveal the hydration structure of the radium(II) ion

open access: yesiScience, 2022
Summary: Radium is refocused from the viewpoint of an environmental pollutant and cancer therapy using alpha particles, where it mainly exists as a hydrated ion.
Akiko Yamaguchi   +14 more
doaj   +1 more source

Atomically Dispersed Ni Site Catalysts Accelerating Sluggish Sulfur Redox Kinetics in Nonaqueous Zn‐S Batteries

open access: yesAdvanced Functional Materials, EarlyView.
An atomically dispersed Ni catalyst featuring Ni‐N4 coordination is developed as a sulfur host for nonaqueous Zn─S batteries. This configuration modulates the electronic structure to lower activation barriers during rate‐limiting steps and promotes a robust ZnF2‐rich cathode‐electrolyte interphase, thereby accelerating sulfur redox kinetics ...
Junhyuk Ji   +7 more
wiley   +1 more source

X-ray absorption spectroscopy of lanmodulin-derived peptides bound to rare earth elements

open access: yesJournal of Synchrotron Radiation
A sustainable and robust supply chain of rare earth elements (REEs) is necessary to meet our consumer, national security and clean energy goals. However, current intra-REE separation technologies (e.g.
Adam Smerigan   +4 more
doaj   +1 more source

Coordinated Architectural and Chemical Reinforcement in the Crushing Mandible of a Soldier Termite

open access: yesAdvanced Functional Materials, EarlyView.
The crushing mandible of a soldier termite withstands substantial biting loads despite lacking mineral. Its cuticle is partitioned: convex teeth pair hardness and zinc enrichment with aligned chitin fibers for contact durability, while stiffer concave regions between teeth carry bending loads.
Andrew Tran Nguyen   +16 more
wiley   +1 more source

Interpretation of EXAFS Data

open access: yesJournal of Synchrotron Radiation, 1995
An outline of the theory of X-ray absorption as applied to X-ray absorption spectroscopy is given, concentrating on EXAFS, showing how structural parameters are contained within the theory. A full description of the scattering problem and of inelastic effects is also included, and a description is given of how structural information may be extracted ...
openaire   +2 more sources

Mixed‐Metal Promotion in a Manganese‐Molybdenum Oxynitride as Catalyst to Integrate C─C and C─N Coupling Reactions for the Direct Synthesis of Acetonitrile from Syngas and Ammonia

open access: yesAdvanced Materials, EarlyView.
Transition metal oxy/carbo‐nitrides show great promise as catalysts for sustainable processes. A Mn‐Mo mixed‐metal oxynitride attains remarkable performance for the direct synthesis of acetonitrile, an important commodity chemical, via sequential C─N and C─C coupling from syngas (C1) and ammonia (N1) feedstocks.
M. Elena Martínez‐Monje   +7 more
wiley   +1 more source

Oxidation Behavior of Platinum Group Alloys in Molten Glass

open access: yesElectrochemistry
The composition of platinum group alloys in insoluble residue liquid waste produced during spent nuclear fuel reprocessing depends on the type of fuel and the degree of burn-up.
Koya YAMAZAKI   +4 more
doaj   +1 more source

Tuning Amorphous‐Crystalline Catalytic Interfaces by Mechanochemistry: Cu‐Based Metallic Glasses Coupled with Ceria for CO Oxidation

open access: yesAdvanced Materials, EarlyView.
Ball‐milling Cu‐based metallic glasses with ceria creates a unique nanostructure where metallic glass particles are wrapped by CeO2 nanoparticles. The intimate integration triggers copper state reorganization during reaction and aging, boosting CO oxidation and COPrOx activity.
Maahin Mirzay‐Shahim   +17 more
wiley   +1 more source

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