Results 41 to 50 of about 484 (218)

The state of palladium and copper on the surface of freshly prepared low temperature carbon monoxide oxidadation catalyst PdCl₂-CuCl_2/γ-Al₂O₃

Тонкие химические технологии, 2010
The EXAFS/XANES, XRD, SEM methods were used for examination of freshly prepared low temperature carbon monoxide oxidation in air catalyst PdCl2-CuCl2/γ-Al2O3 active components states.
D. N. Titov, L. G. Bruk, I. V. Oshanina, O. N. Temkin, G. M. Kuz’micheva, Ya. V. Zubavichus, A. A. Veligzhanin, N. V. Sadovskaya   +7 more
doaj  

In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts

Advanced Materials, EarlyView.
An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea, Jordan Santiago Martinez, M. Asunción Molina, Jaime Mazarío, Lucy Costley‐Wood, Christian Cerezo‐Navarrete, Carlo Marini, Eduardo Villalobos‐Portillo, Andrew M. Beale, Pascual Oña‐Burgos   +9 more
wiley   +1 more source

Effectiveness of ab initio molecular dynamics in simulating EXAFS spectra from layered systems

Journal of Synchrotron Radiation
The simulation of EXAFS spectra of thin films via ab initio methods is discussed. The procedure for producing the spectra is presented as well as an application to a two-dimensional material (WSe2) where the effectiveness of this method in reproducing ...
F. d'Acapito, M. A. Rehman
doaj   +1 more source

Phase Engineering of Nanomaterials (PEN): Evolution, Current Challenges, and Future Opportunities

Advanced Materials, EarlyView.
This review summarizes the synthesis, phase transition, advanced characterization spanning ex situ to in situ and operando techniques, and diverse applications of phase engineering of nanomaterials (PEN). It further outlines key challenges and future opportunities, such as phase stability, architecture control, and artificial intelligence (AI)‐driven ...
Ye Chen, Zhanxi Fan, Jingjie Ge, Qiyuan He, Zhuangchai Lai, Jiawei Liu, Chaoliang Tan, Hua Zhang   +7 more
wiley   +1 more source

Improving sensitivity of XANES structural fit to the bridged metal–metal coordination

Journal of Synchrotron Radiation
Hard X-ray absorption spectroscopy is a valuable in situ probe for non-destructive diagnostics of metal sites. The low-energy interval of a spectrum (XANES) contains information about the metal oxidation state, ligand type, symmetry and distances in the ...
S. V. Abrosimov, B. O. Protsenko, A. S. Mannaa, V. G. Vlasenko, S. A. Guda, I. A. Pankin, A. S. Burlov, Y. V. Koshchienko, A. A. Guda, A. V. Soldatov   +9 more
doaj   +1 more source

Mechanisms of Copper and Mercury Adsorption on Bentonite Clays from EXAFS Spectroscopy

Chemical Engineering Transactions, 2014
Copper(II) and Mercury(II) cations are classified as important heavy metal pollutants in industrial wastewaters. In this study, Extended X-Ray Absorption Fine Structure (EXAFS) spectroscopy was used to provide information about the coordination ...
M.G.A. Vieira, A.F. de Almeida Neto, M.G.C. da Silva   +2 more
doaj   +1 more source

Escaping the Scaling Relationships in Oxygen Reduction Catalysis: Implications for PEM Fuel Cells

Advanced Materials, EarlyView.
Escaping the scaling relationships of the oxygen reduction reaction is vital for hydrogen fuel cells. This outlook examines how interfacial heterogeneity, spanning the subsurface lattice, chemisorption layer, and near‐interface solvation volume, mechanistically decouples intermediate binding energetics.
Muhammad Bilal Wazir, Lourdes F. Vega, Maryam Khaleel   +2 more
wiley   +1 more source

Cu‐Pd Dual Single Atoms Promoting Selective CO2 Photoreduction to C2 Products in Seawater

Advanced Materials, EarlyView.
Cu and Pd dual single atoms anchored on TiO2 cooperatively enhance C─C coupling during CO2 photoreduction in seawater. Under xenon‐light irradiation and without a sacrificial reagent/alkaline trapping agent, the catalyst achieves highly selective acetic acid formation.
Elhussein M. Hashem, Yiran Jiao, Amin Talebian‐Kiakalaieh, Xin Xu, Shiying Ren, Teng Liang, Wenzhong Ji, Teng Lu, Yun Liu, Bingquan Xia, Ashley Slattery, Jingyu Wang, Feiyan Xu, Ping She, Yan Jiao, Jingrun Ran   +15 more
wiley   +1 more source

Sustainable and Multifunctional Natural Macromolecular Polymers for Aqueous Zn Metal Batteries

Advanced Materials, EarlyView.
We comprehensively review the structure‐function relationships and regulatory mechanism of natural macromolecular polymers in stabilizing zinc anodes at the microscopic and mesoscopic scales. The interactions among polymer structures, optimization strategies, and regulatory mechanisms are discussed systematically summarizing recent related research ...
Yunuo Shi, Bo Jiang, Jingcheng Zhang, Xiaodong Shao, Peixun Xiong, Lutong Shan, Shengyang Huang, Mengfang Liang, Mengyao Chang, Fangyan Liu, Wenwu Li, Baoyu Xia, Wei Ji, Ho Seok Park   +13 more
wiley   +1 more source

Defect‐Engineered Microwave‐Responsive Ni@C Composites From Waste PET for Catalytic Plastic Upcycling

Advanced Materials, EarlyView.
A circular upcycling strategy transforms waste poly(ethylene terephthalate) bottles into microwave‐responsive Ni@C catalyst featuring lattice‐distorted nickel cores and defective carbon shells. These strain‐rich heterointerfaces enhance dielectric loss and promote localized microwave hotspots, accelerating peroxymonosulfate activation and polymer‐chain
Xiao Lu, Shiying Ren, Jingkai Lin, Kunsheng Hu, Yalan Mo, Shaobin Wang, Wenjie Tian, Xiaoguang Duan   +7 more
wiley   +1 more source