Intramolecular N···F Pnictogen Bond Mitigates the Explosive Behavior of Azido‐L‐Phenylalanines
An intramolecular N···F pnictogen bond is the key for the chemical stabilization of the fluorinated azido‐L‐phenylalanines, mitigating the risk of explosion and thus facilitating the handling and storage of these materials. Organic azides are versatile intermediates but are plagued by intrinsic instability and potential explosiveness. Here, it is shown
Andrea Pizzi +5 more
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High-temperature chemical oxidation pathways in lithium-ion batteries: mechanistic insights into ethylene carbonate decomposition. [PDF]
Schmidt L +8 more
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A new way of obtaining mixed 13/14/15 hydride containing compounds stabilized only by a Lewis base is presented. The functionalization of IDipp·BH2PH2 (IDipp = 1,3‐Bis‐(2,6‐diisopropylphenyl)‐imidazolin‐2‐ylidene) by main group electrophiles leads to the formation of the compounds [IDipp·BH2PH2E]+ [E = H, CH3 SiEt3, Ge(SiMe3)3, SnMe3) which represent a
Robert Szlosek +7 more
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Conformational constraints in [Ni(P<sup>R</sup> <sub>2</sub>N<sup>R'</sup> <sub>2</sub>)<sub>2</sub>] complexes for tuning H<sub>2</sub> production and oxidation: a DFT-based ligand design study. [PDF]
Hadsadee S +8 more
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Biosynthesis of Silver Nanoparticles Using Black Pepper (Piper nigrum) Seed Extract and Evaluation of Their Cytotoxicity. [PDF]
Maciel NF +17 more
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Aqueous Solutions of Oil-Soluble Polyglycerol Esters: Structuring and Emulsifying Abilities. [PDF]
Stanimirova R +3 more
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Thermal-electrical multiphysics modeling of ZnO/mesoporous carbon nanocomposite anodes for lithium-ion batteries. [PDF]
Abushuhel M +7 more
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Alginate Hydrogel with Pluronic F-68 Enhances Cryopreservation Efficiency in Peach Germplasm. [PDF]
Bobrova O +6 more
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