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Apuntes de cinética y catálisis [PDF]

open access: yes, 2017
1 archivo PDF (52 páginas)"La cinética química es un tema o área de la fisicoquímica, la cual es una rama de la química. La Fisicoquímica moderna tiene firmes bases en la Física pura.
Fernández Sánchez, Lilia   +1 more
core  

A Talc- and Kaolin-Enriched Acetylated Starch Biocoating: An Alternative to Single-Use Plastic for the Food Industry

open access: yesPolysaccharides
The increasing production of plastics, driven by modern societal development, has resulted in a significant rise in plastic waste, which poses serious environmental concerns due to its lengthy degradation times.
Antonio Veloso-Fernández   +3 more
doaj   +1 more source

Vibrational assignments of two polymorphic forms of metaxolone by using DFT calculations and the SQM methodology [PDF]

open access: yes, 2018
A theoretical study has been performed on the musclerelaxant 5-[(3, 5-dimethylphenoxy)methyl]-1,3-oxazolidin-2-one, of generic name metaxolone (MTX), by using the hybridB3LYP/6-31G calculations in the gas phase and theexperimental available infrared and ...
Brandan, Silvia Antonia   +3 more
core  

Pd/Cu Single Atom Alloys for Selective Alcohol Dehydrogenation: From Single Crystalline to Nanostructured Model Catalysts

open access: yesAngewandte Chemie, Volume 138, Issue 5, 28 January 2026.
Model Pd/Cu single atom alloy catalysts were prepared in nanostructured form and structurally characterized. They show an outstanding performance in dehydrogenating butanol to butanal with 100% selectivity – the property that cannot be reproduced over simplified single crystalline Pd/Cu(111) counterparts.
Philipp A. Fredersdorff   +7 more
wiley   +2 more sources

Sulfur‐Induced Lattice Modulation and Charge‐Transport Enhancement in MnO2 Nanowires for Hybrid Energy Storage

open access: yesEnergy Storage, Volume 8, Issue 1, February 2026.
ABSTRACT In this study, sulfur‐modified MnO2 nanowires (MnO2‐S) were synthesized via a two‐step hydrothermal and solid‐state process and evaluated as battery‐type electrodes for hybrid supercapacitors. Transmission electron microscopy (TEM) and high‐resolution TEM confirmed morphological integrity, while structural changes induced by sulfur inclusion ...
Jhonatam Pinheiro Mendonça   +6 more
wiley   +1 more source

Integrated green extraction of phenolic compounds and fermentable sugars from grapefruit peel using ultrasound and enzymatic hydrolysis

open access: yesJournal of the Science of Food and Agriculture, Volume 106, Issue 3, Page 1839-1851, February 2026.
Abstract BACKGROUND Valorizing sugar‐rich food waste in biorefineries offers a sustainable route to bio‐based products. Grapefruit peel (GP), representing about 50% of the fruit's weight, is rich in sugars (soluble and insoluble) and polyphenols such as flavonoids.
María del Prado García‐Aparicio   +2 more
wiley   +1 more source

Enzymes of glycolysis and the pentose phosphate pathway as targets of oxidants: Role of redox reactions on the carbohydrate catabolism

open access: yesRedox Biochemistry and Chemistry
Redox reactions can modulate metabolic and signaling pathways with consequences on cellular adaptation to different stimuli. The abundance and structural features of some metabolic enzymes make these targets of oxidants, including one- and two-electron ...
Eduardo Fuentes-Lemus   +3 more
doaj   +1 more source

Bio‐Based Citrate Plasticizers as Nucleating Agents for PLA Fibers: Unlocking Antioxidant and Antimicrobial Potential

open access: yesMacromolecular Chemistry and Physics, Volume 227, Issue 3, 16 February 2026.
Uniform and bead‐free PLA fibers containing functional biobased plasticizers for potential application in food packaging are prepared by force‐spinning technique. ACETEM and CITREM commonly used as food additives are employed within the fibers to provide such functional properties to the fiber mats.
Ignacio Mena‐Prado   +7 more
wiley   +1 more source

Theoretical Study of Electrostatic Embedding and Properties of a Novel Quinolinone‐Chalcone Crystal and a Comparative Analysis with Dihydroquinolinone Analogs

open access: yesChemistryOpen, Volume 15, Issue 2, February 2026.
This graphical abstract highlights the molecular framework, electronic features, and nonlinear optical response of the quinolinone–chalcone crystal QCCP. The left panel displays the full molecular structure and the electrostatic environment introduced by iterative charge embedding, illustrating the crystal‐packing–induced dipole enhancement observed in
Clodoaldo Valverde   +9 more
wiley   +1 more source

Photocatalyzed Ring Expansion of α‐Ketosulfonylaziridines: Ready Access to δ‐Sultams

open access: yesAngewandte Chemie, Volume 138, Issue 4, 22 January 2026.
A novel radical–polar crossover (RPC) photoredox‐catalyzed reaction for the synthesis of δ‐sultams from N‐sulfonyl α‐ketoaziridines through a controlled ring opening–expansion process is presented. This method allows the easy access to sultams with an unprecedented substitution pattern in up to 85% yield and 2:1 d.r., and highlights the potential of ...
Marco M. Mastandrea   +7 more
wiley   +2 more sources

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