Results 191 to 200 of about 184,978 (350)

Water‐Mediated 1,7‐Palladium Aryl‐to‐Aryl Migration in an Unusual Aryne Trimerization Enables the Synthesis of Multihelicenes with Profoundly Hindered Stereogenic Axes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
In the presence of a Pd0 catalyst, large π‐extended arynes trimerize in an unusual manner to forge extremely compact and strained chiral benzenoids. This new trimerization reaction involves a 1,7‐Pd isomerization, a rare and poorly understood process that is elucidated.
Albert Artigas   +6 more
wiley   +1 more source

Redrawing the Mannich‐Type Reaction through Carbonyl Umpolung Reactivity

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
GA: Herein, a conceptually novel one‐pot multicomponent strategy is reported for the streamlined construction of five‐membered imidazolidines from 1,2‐diaza‐1,3‐dienes (onefold), amines (twofold), and formaldehyde (twofold). This redesigned Mannich‐type reaction that exploits a carbene‐like activity of 1,2‐diaza‐1,3‐dienes (realized by “umpolung ...
Vittorio Ciccone   +4 more
wiley   +1 more source

Cu(I)‐Catalyzed Interrupted Cycloaddition Between Azides, Ag(I)‐Acetylides, and Diorganoyl Dichalcogenides

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Unleashing the power of Ag(I)‐acetylides with LiCl/dimethyl sulfoxide (DMSO). The LiCl/DMSO mixture have an unexplored ability to dramatically increase the solubility of Ag(I)‐acetylides regardless of their molecular structure, which is explored to achieve high chemoselectivity in the Cu(I)‐catalyzed interrupted cycloaddition between organic azides, Ag(
Diego Seckler   +8 more
wiley   +1 more source

Sustainable Lignin@ZnO Hybrid Materials: Synthesis, Characterization, and Preliminary Biostimulant Assessment in Tomato Plants

open access: yesAdvanced Sustainable Systems, EarlyView.
This study explores the synthesis of lignin‐based ZnO hybrid materials, combining the bioactive potential of lignin with the role of zinc as a plant micronutrient. In vivo experiments on tomato plants highlighted the controlled nutrient delivery capacity of the hybrid compared to ZnO alone.
Marianna Vescovi   +11 more
wiley   +1 more source

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