Calcium‐Mechanochemistry Enabled Ketone Synthesis From Organic Iodides and Carboxylic Acids
Mechanochemically generated organocalcium species display unusual chemoselectivity toward carboxylates, enabling direct ketone synthesis without overaddition. Ball milling activates commercial calcium metal under ambient, solvent‐minimized conditions, providing a broad substrate scope, high functional‐group tolerance, and a practical one‐step ...
Mengyao Pei +9 more
wiley +1 more source
Alkaline-Promoted Hydrothermal Liquefaction of Polo Horse Manure for Biocrude Production. [PDF]
Namsiri P, Pianthong K, Thanakijkasem P.
europepmc +1 more source
Pd‐Catalyzed Asymmetric Dearomative Heck/Tsuji‐Trost Difunctionalization of Naphthalenes
We have developed a palladium‐catalyzed asymmetric dearomative Heck/Tsuji‐Trost 1,4‐difunctionalization reaction of naphthalenes, affording 4‐aminospirocyclohexene oxindole products bearing two remote chiral centers. Through the effect of the newly designed chiral sulfinamide phosphine ligand with large steric hindrance, side reactions are inhibited ...
Long‐Ling Ma +3 more
wiley +1 more source
Beyond petrochemicals: challenges and opportunities in industrial-scale biomanufacturing. [PDF]
Kim JY, Yu HE, Kim MH, Lee SY.
europepmc +1 more source
Efficient Adsorption‐Based Direct Air Capture Via Triply Periodic Minimal Surface Architectures
Architected triply periodic minimal surface (TPMS) contactors reshape direct air capture by replacing straight‐channel diffusion limits with convection‐enhanced CO2 transport. Chaotic advection thins boundary layers and exposes fast adsorption sites, enabling 70%–75% more fast sites, 114% higher productivity, and 51.8% lower energy consumption than ...
Qingyang Shao +6 more
wiley +1 more source
Analysis of trade-offs of post-sorting plastic packaging. [PDF]
Schmuck A +5 more
europepmc +1 more source
Cation Diffusion‐Mediated Displaced Reaction‐Transformation in Green Steelmaking
The removal of O lattice atoms by environmental H2 at the surface of Fe3O4 results in Fe enrichment, driving the inward diffusion of Fe cations into the bulk. Through hopping between unoccupied and initially occupied sites, cation diffusion triggers a spatially displaced reaction‐transformation and drives subsequent dynamic phase transformations and ...
Guangyi Guo +7 more
wiley +1 more source
Integrated torrefaction-anaerobic digestion of bamboo waste for enhanced energy recovery: process optimization, product characterization, and techno-economic evaluation. [PDF]
Kachroo H +4 more
europepmc +1 more source
A flexible PDMS‐LATP polymer‐ceramic membrane creates lithium‐ion “superhighways” for rapid and selective extraction from complex brines. The amorphous PDMS matrix suppresses nonselective leakage and stabilizes the ceramic network, while LATP provides preferential Li+ conduction.
Xinxin Wei +12 more
wiley +1 more source
Assessing Biomass-Based Methanol Production via Electrified Gasification and Solar-Assisted CO<sub>2</sub> Utilization. [PDF]
Jadoon UK +5 more
europepmc +1 more source

