Results 221 to 230 of about 122,396 (311)

Beyond Formate Trapping: A Mechanistic Framework for Homogeneous CO2‐to‐Methanol Conversion With First‐Row Transition Metals

open access: yesAngewandte Chemie, EarlyView.
This review shows that converting CO2 into methanol with catalysts based on abundant first‐row metals requires more than overcoming formate formation. Success depends on balancing hydrogen activation, intermediate reactivity, product release, and catalyst stability.
Elise Boudry, Christophe M. Thomas
wiley   +1 more source

Mechanochemical Defluorination of Polytetrafluoroethylene (PTFE) With Base Metals

open access: yesAngewandte Chemie, EarlyView.
Polytetrafluoroethylene (PTFE) mechanochemically reacts with safe‐to‐handle, abundant, and inexpensive base metals Zn and Al, as well as with metals like Cd and Pb, to produce sp2‐carbon and industrially important metal fluorides. The reactivity presents PTFE as a mechanochemical fluorination agent, with opportunities for closed‐loop reductive ...
Anže Zupanc   +10 more
wiley   +1 more source

Disorder Beats Order: Carbon Microstructure Steers Radical Versus Cationic Pathways in Kolbe Electrolysis

open access: yesAngewandte Chemie, EarlyView.
Less graphitic, more Kolbe: carbon microstructure steers selectivity in Kolbe electrolysis. Disordered, sp3‐rich carbon electrodes with high charge‐transfer resistance favor surface radical pathways, giving about an order of magnitude more Kolbe dimer than graphitized sp2‐rich counterparts.
Md Mosaddek Hossen   +3 more
wiley   +1 more source

Recycling of Flexible Plastic Films: Emergent Technologies. [PDF]

open access: yesPolymers (Basel)
Licht JS, Tsianou M, Alexandridis P.
europepmc   +1 more source

Coacervate Droplet Sequestration of Heterogeneous Nanoplastics With Elastin‐Like Polypeptides

open access: yesAngewandte Chemie, EarlyView.
Phase‐separated polypeptide droplets captured incidental nanoplastics as a reusable nanoplastic sink. The engineered droplets selectively partitioned nanoplastics and exhibited unique interactions depending on droplet type and nanoplastic identity, establishing biopolymer coacervates as a potential platform for nanoplastic characterization and removal.
Natalie R. Ling   +2 more
wiley   +1 more source

Home - About - Disclaimer - Privacy