Stabilization of the Benzene Radical Trianion in an Inverse‐Sandwich Yttrium Complex
A new type of benzene anion state is born: The unprecedented benzene radical trianion embedded in an inverse‐sandwich yttrium complex was synthesized by a one‐electron chemical reduction of its benzene dianion precursor using potassium graphite in the presence of [2.2.2]‐cryptand.
Weiqing Mao +5 more
wiley +2 more sources
Diversity, Equity, and Inclusion Initiatives and Faculty Roles in Orthopaedic Sports Medicine Fellowships Are Associated With Increased Female Representation Among Faculty and Fellows. [PDF]
Lessiohadi NJ +6 more
europepmc +1 more source
Objective Identifying modifiable factors influencing amyotrophic lateral sclerosis (ALS) and frontotemporal dementia (FTD) risk is important for prevention. Blood biomarkers, particularly cholesterol, have been associated with neurodegenerative risk, but findings in ALS are inconsistent, and data on FTD are limited.
Christos V. Chalitsios +5 more
wiley +1 more source
Solar Flow Synthesis of Polymer Nanoparticles: Scaling Local Experiments to Global Potential
The large‐scale sunlight‐induced photochemical synthesis of polymer nanoparticles based on the Diels–Alder step‐growth polymerization of a bismaleimide and a difunctional o‐methylbenzaldehyde in a self‐built solar flow reactor is introduced. Furthermore, a framework is established to translate sunlight‐driven experimental results globally—validated in ...
Jochen A. Kammerer +7 more
wiley +2 more sources
Mechanism of the Photodecomposition of Stable Triarylmethyl Radicals
Photolysis of luminescent chlorinated trityl radicals was studied with density functional theory and the decomposition products were isolated and characterized. It proceeds by a 5‐electron electrocyclization then a 1,8‐sigmatropic chloride shift, forming non‐emissive, less stable fluorenyl radicals.
Hannah E. Hackney +3 more
wiley +2 more sources
Geographic Trends and Geospatial Analysis of Head and Neck Fellowship-Trained Surgeons. [PDF]
Zeitouni J +6 more
europepmc +1 more source
Spring 2016, Gilman Scholarships Broaden Cultural and Academic Horizons [PDF]
UNH Global Education Center
core +1 more source
Engaging Scientists in Science Policy: Experiences From Canada. [PDF]
Lâm S, Raza S, Hansen L.
europepmc +1 more source
Implementing Standardised Training and Education: The Vision of the European Association of Urology Led by the European School of Urology. [PDF]
Somani BK +20 more
europepmc +1 more source

