Results 101 to 110 of about 40,277 (302)

Linkage of α-cyclodextrin-terminated poly(dimethylsiloxanes) by inclusion of quasi bifunctional ferrocene

open access: yesBeilstein Journal of Organic Chemistry, 2013
We report the noncovalent linkage of terminally substituted oligo(dimethylsiloxanes) bearing α-cyclodextrins (α-CD) as host end groups for the cyclopentadienyl rings of ferrocene.
Helmut Ritter   +2 more
doaj   +1 more source

Expanding Cyanide‐Bridged Weakly Coordinating Anions Through the Brominated Silver Salt Ag[BCNBBr]

open access: yesChemistry – A European Journal, EarlyView.
The brominated weakly coordinating anion [μ‐(CN)(B(C6F4Br)3)2] ([BCNBBr]−), based on two B(C6F4Br)3 units bridged by cyanide, is obtained as its silver salt Ag[BCNBBr] from CH2Cl2. Ag[BCNBBr] enables oxidation and halide abstraction reactions, affording diverse [BCNBBr]− salts with oxidizing and electrophilic cations.
Amina L. Moshtaha   +4 more
wiley   +1 more source

Synergistic Photo‐Electro‐Fenton Oxidation of Antibiotics Using a Ferrocene‐Functionalized MXene (Ti3C2Tx) Electrode

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
2D MXene (Ti3C2Tx)‐based electrode setup for hybrid photo‐electro‐Fenton degradation of antibiotic (tetracycline). The persistence of antibiotics such as tetracycline in aquatic systems poses severe environmental and health risks by potential antimicrobial resistance.
Durga Sankar Vavilapalli   +8 more
wiley   +1 more source

Single Atom‐Modified TiO2‐Based Catalysts for Photoelectrochemical Water Splitting: From Fundamentals to Future Prospects

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Hydrogen and oxygen generated from water splitting process by photoelectrocatalysis of single atom modified TiO2 based photoelectrocatalysts. The accelerating demand for green hydrogen has intensified the development of efficient and durable photoelectrocatalysts (PECs) for sustainable water splitting.
Zichu Zhao   +2 more
wiley   +1 more source

Next‐Generation Carbon‐Based Anodes for Alkali Metal‐Ion Batteries: Recent Progress on Biphenylene and Emerging Materials

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Recent advances in carbon‐based anodes for alkali metal‐ion batteries are critically reviewed, with emphasis on biphenylene and other emerging carbon allotropes. Biphenylene exhibits exceptional theoretical electrochemical properties beyond conventional graphite, highlighting its strong potential as a next‐generation anode material once scalable ...
Adewale Hammed Pasanaje, Nirpendra Singh
wiley   +1 more source

The Synthesis of Tetrakis(N,N-dimethylaminomethyl)ferrocene and Its Bimetallic Nickel(II) Dichloride Complex: The Search for Precursors for Methoxycarbonylation Ligands

open access: yesInorganics
The family of N,N-dimethylaminomethylferrocene compounds is one of the most important in ferrocene chemistry. They serve as precursors for a range of anti-malarial and anti-tumour medicinal compounds, in addition to being key precursors for ferrocene ...
Ian R. Butler   +5 more
doaj   +1 more source

Gold(I) Phosphine/Phosphido‐Borohydride Complexes

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Synthesis, structure, and electrochemical characteristics of a homologous series of gold(I) complexes featuring phosphine and phosphido–borohydride ligands. A homologous series of linear, mononuclear gold(I) phosphine/phosphido‐borohydride complexes, encompassing [Au(PR3)2]+ 1, [Au(PR3)(PR2BH3)] 2 and [Au(PR2BH3)2]– 3 (R = tBu, Ad), has been prepared ...
Matthew J. G. Sinclair   +3 more
wiley   +1 more source

FERROCENES AS HAEMATINICS [PDF]

open access: yesBritish Journal of Pharmacology and Chemotherapy, 1965
openaire   +2 more sources

Redox‐Active Bisphosphines Based on a W(II)‐Propargyl Complex Backbone

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Three bisphosphine ligands based on tungsten(II) propargyl‐type alkyne complexes were synthesized and characterized. The methanolate derivative was used as a metalla‐ligand for the preparation of a binuclear bisphosphine‐κ2‐PdCl2 complex. In both cases, IR spectroelectrochemistry (IR‐SEC) measurements revealed a successive process following oxidation ...
Friederike M. Hamann   +7 more
wiley   +1 more source

Artificial [FeFe]‐Hydrogenase Mimics From Ferrocenyl Thioketone‐Functionalized Triphenylamine and (Bi)thiophene Derivatives: Synthesis, Characterization, and Hydrogen Evolution Catalysis

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Synthesis of ferrocenyl thioketone‐functionalized triphenylamine and triphenylamine‐(bi)thiophene derivatives as proligands for the assembly of artificial [FeFe]‐hydrogenase active site models. Thiocarbonyl compounds, especially thioketones, have emerged as promising precursors for constructing [FeFe]‐hydrogenase mimics that can mediate hydrogen ...
Hassan Abul‐Futouh   +5 more
wiley   +1 more source

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