Results 81 to 90 of about 54,509 (296)

Current applications and future potential for bioinorganic chemistry in the development of anticancer drugs [PDF]

, 2009
This review illustrates notable recent progress in the field of medicinal bioinorganic chemistry as many new approaches to the design of innovative metal-based anticancer drugs are emerging.
Aird, Ang, Barnard, Barnes, Bednarski, Bergamo, Bergamo, Bindoli, Campone, Chatterjee, Che, Chen, Chen, Chen, Chen, Choy, Clarke, Cordier, Desoize, Detty, Dougan, Ernst, Failes, Farrer, Feazell, Fricker, Gabbiani, Gunatilleke, Hall, Hambley, Hamelers, Henderson, Hillard, Hotze, Hotze, Jakupec, Jakupec, Junicke, Kelland, Kostenich, Kostova, Kostrhunova, Li, Mackay, Mackay, Meggers, Mosi, Nguyen, Noor, Oliveira, Ott, Ott, Ott, Peacock, Peacock, Peacock, Peter J. Sadler, Petzold, Petzold, Powis, Rademaker-Lakhai, Sabine H. van Rijt, Sadler, Saggioro, Sergeant, Sessler, Sharman, Shaw, Sherman, Smalley, Storr, Urig, van Rijt, Vessieres, Wang, Wang   +75 more
core   +1 more source

Structural Modulation of Charge Transfer in Donor–Acceptor Systems: Effects of Donor Type and Connectivity

Advanced Optical Materials, EarlyView.
A coherent phthalimide acceptor platform with planar (Cz—carbazole) and spiro‐type (SAF—spiroacridine fluorene) donors enables systematic tuning of donor geometry and coupling, driving the evolution of excited‐state topology from classical CT‐TADF and fluorescence/RTP to CT‐driven and LE‐assisted TADF with OLED efficiencies ≈ 36%.
Christopher Anton Wallerius, Robert Herzhoff, Soyoung Boo, Andreas Mischok, Dirk Hertel, Jörg‐Martin Neudörfl, Daniele Fazzi, Malte C. Gather, Klaus Meerholz   +8 more
wiley   +1 more source

Deprotonative C(sp3)/C(sp2)–H (Multi)Silylation of (Hetero)Arenes Mediated by NaTMP

Angewandte Chemie, EarlyView.
An operationally simple protocol using a strongly basic sodium amide in combination with sterically emcumbered silicon electrophiles enables the deprotonative C–H (multi)silylation of a myriad of (hetero)arenes. Mechanistic investigations highlight the pivotal role of steric and coordination effects in controlling the regioselectivity and efficiency of
David Sánchez‐Roa, Sophia Belrhomari, Ana McGinley, Clevin Anto Liju, Manting Mu, Max García‐Melchor, Eva Hevia   +6 more
wiley   +2 more sources

A Density Functional Theory based study of Electron Transport Through Ferrocene Compounds with Different Anchor Groups in Different Adsorption Configurations of A STM-setup

, 2018
In our theoretical study where we combine a nonequilibrium Green's function (NEGF) approach with density functional theory (DFT) we investigate compounds containing a ferrocene moiety which is connected to i) thiol anchor groups on both sides in a para ...
Stadler, Robert, Zhao, Xin
core   +1 more source

Methyl 2-[(ferrocenylcarbonyl)amino]thiophene-3-carboxylate [PDF]

, 2005
The title compound, [Fe(C₅H₅)(C₁₂H₁₀NO₃S)], was synthesized from ferrocenecarboxylic acid and methyl 2-aminothiophene-3-carboxylate in modest yield. The substituted ring system is essentially planar through the amidothienylcarboxylate moiety, η⁵-(C₅H₄ ...
Alley, Steven, Gallagher, John F., Kenny, Peter T.M., Lough, Alan J.   +3 more
core   +1 more source

Stabilization of Single Metal Atoms on Graphitic Carbon Nitride: Synthetic Strategies and Emerging Applications

Advanced Science, EarlyView.
This review highlights recent advancements in stabilizing single metal atoms on graphitic carbon nitride emphasizing innovative synthesis strategies and emerging applications in electrocatalysis, photocatalysis and organic transformations, along with key challenges and future perspective. Abstract Emerging as a new frontier in catalysis science, single‐
Wenyao Zhang, Junjie Cui, Zhenjie Yao, Boyuan Zhu, Nithinraj Panangattu Dharmarajan, Ajayan Vinu, Junwu Zhu   +6 more
wiley   +1 more source

Monomeric and dimeric anhydride-functionalized ferrocene: synthesis and structural analysis

Journal of Taibah University for Science
A series of mono-substituted ferrocene-based anhydrides of the general formula FcCO2COAr (Fc = Fe(η5-C5H5)(η5-C5H4); Ar = Ph (1a), 4-Cl-C6H4 (1b), 4-CH3-C6H4 (1c)) were synthesized by acyl substitution of ferrocene carboxylic acid with the corresponding ...
Mohammad El-khateeb, Matteo Cardoso, Frank Schaper   +2 more
doaj   +1 more source

An investigation into the unusual linkage isomerization and nitrite reduction activity of a novel tris(2-pyridyl) copper complex [PDF]

, 2017
The copper-containing nitrite reductases (CuNIRs) are a class of enzymes that mediate the reduction of nitrite to nitric oxide in biological systems. Metal–ligand complexes that reproduce the salient features of the active site of CuNIRs are therefore of
Roger, Isolda, Senn, Hans M., Sproules, Stephen, Symes, Mark D., Wilson, Claire   +4 more
core   +2 more sources

Plasma decomposition of ferrocene

The Journal of Chemical Physics
Ferrocene [Fe(C5H5)2 or FeCp2] is a well-known precursor molecule for iron in vapor deposition of iron containing films by, e.g., chemical vapor deposition (CVD) processes. CVD processes often use the energy in plasma discharges to decompose precursor molecules, which allows lowering the substrate temperature for deposition on sensitive materials ...
Pentti Niiranen, Felicia Andersson, Daniel Lundin, Lars Ojamäe, Henrik Pedersen   +4 more
openaire   +3 more sources

Oligomeric ferrocene rings

Nature Chemistry, 2016
Cyclic oligomers comprising strongly interacting redox-active monomer units represent an unknown, yet highly desirable class of nanoscale materials. Here we describe the synthesis and properties of the first family of molecules belonging to this compound category-differently sized rings comprising only 1,1'-disubstituted ferrocene units (cyclo[n], n ...
Michael S. Inkpen, Stefan Scheerer, Michael Linseis, Andrew J. P. White, Rainer F. Winter, Tim Albrecht, Nicholas J. Long   +6 more
openaire   +4 more sources