Results 61 to 70 of about 15,082 (256)

Comparative Insights and Overlooked Factors of Interphase Chemistry in Alkali Metal‐Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
This review presents a comparative analysis of Li‐, Na‐, and K‐ion batteries, focusing on the critical role of electrode–electrolyte interphases. It especially highlights overlooked aspects such as SEI/CEI misconceptions, binder effects, and self‐discharge relevance, emphasizing the limitations of current understanding and offering strategies for ...
Changhee Lee   +3 more
wiley   +1 more source

Proteome‐Wide Target Identification Using Reactive Metallo‐Scaffolds (r‐mS): A Platform for Metallodrug Discovery

open access: yesAngewandte Chemie, EarlyView.
Re‐envisioning the Ligandable Proteome: Reactive Metallo‐Scaffolds (r‐mS) combine non‐covalent protein engagement by a metallo‐scaffold with covalent cysteine capture through a tethered chloroacetamide warhead. Chemoproteomic profiling reveals unique enzyme engagement including ligases, kinases and methyltransferases, highlighting opportunities for ...
Jessica E. Waters   +15 more
wiley   +2 more sources

Monomeric and dimeric anhydride-functionalized ferrocene: synthesis and structural analysis

open access: yesJournal of Taibah University for Science
A series of mono-substituted ferrocene-based anhydrides of the general formula FcCO2COAr (Fc = Fe(η5-C5H5)(η5-C5H4); Ar = Ph (1a), 4-Cl-C6H4 (1b), 4-CH3-C6H4 (1c)) were synthesized by acyl substitution of ferrocene carboxylic acid with the corresponding ...
Mohammad El-khateeb   +2 more
doaj   +1 more source

Degradation Pathways of Silicon‐Based Anodes in Lithium‐Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
Silicon‐based anodes undergo degradation through five primary pathways: (1) mechanical and structural deterioration of the active material, (2) loss of electrode integrity and electrical contact, (3) mechanical instability of the solid electrolyte interphase (SEI), characterized by repetitive fracture and deformation, (4) chemical instability of the ...
Yoon Jeong Choi   +3 more
wiley   +1 more source

Ferrocene

open access: yes, 2011
The structure of ferrocene was famously analysed by Woodward and Wilkinson in 1952,, symmetrically straddled in history by Pauling (1951) and Watson and Crick (1953). Quite a trio of Nobel-prize winning molecular structural analyses, all based on a large dose of intuition.
openaire   +2 more sources

Multivalent Lactose–Ferrocene Conjugates Based on Poly (Amido Amine) Dendrimers and Gold Nanoparticles as Electrochemical Probes for Sensing Galectin-3

open access: yesNanomaterials, 2020
Galectin-3 is considered a cancer biomarker and bioindicator of fibrosis and cardiac remodeling and, therefore, it is desirable to develop convenient methods for its detection.
Manuel C. Martos-Maldonado   +3 more
doaj   +1 more source

Molecular Design Strategies for High‐Voltage Organic Cathodes

open access: yesAdvanced Energy Materials, EarlyView.
This work proposes molecular engineering strategies for high‐voltage organic cathode materials for Li‐ion batteries: (1) increase Li‐O coordination number (CN), (2) achieve a greater increase in aromaticity upon reduction (∆Aromaticity), and (3) add an electron‐withdrawing group (EWG), through a combined experimental and computational study on reported
Sungil Hong   +8 more
wiley   +1 more source

Oligomeric ferrocene rings

open access: yesNature Chemistry, 2016
Cyclic oligomers comprising strongly interacting redox-active monomer units represent an unknown, yet highly desirable class of nanoscale materials. Here we describe the synthesis and properties of the first family of molecules belonging to this compound category-differently sized rings comprising only 1,1'-disubstituted ferrocene units (cyclo[n], n ...
Michael S. Inkpen   +6 more
openaire   +4 more sources

High Sensitive Sandwich-type Electrochemical IgG Immunosensor Based on a Nanocomposite of Carbon Nanotube and Multifunctional Ionic Liquid Containing Aldehyde and Ferrocene Groups as Labels

open access: yesInternational Journal of Electrochemical Science, 2018
Using a nanocomposite of carbon nanotube and multifunctional ionic liquid as labels and chitosan as platform, we fabricated a sandwich-type electrochemical immunosensor.
Youming Shen, Guangyu Shen, Youyu Zhang
doaj   +1 more source

Palladium-catalyzed intramolecular C–H arylation of ferrocenyl-sulfides, sulfoxide and its application in metal ion recognition

open access: yesGreen Synthesis and Catalysis
An intramolecular C–H arylation of ferrocenyl ortho-bromophenyl sulfide and sulfoxide has been developed with a palladium/non-chiral monophosphine ligand. Under mild reaction conditions, a wide range of ferrocene cyclosulfide and ferrocene cyclosulfoxide
Feifei Cao   +6 more
doaj   +1 more source

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