Results 111 to 120 of about 144,912 (267)

Clustomesogen Showing Sub‐Zero Liquid Crystal Properties: Supramolecular Assembly Between Cs2[Mo6Ii8(OCOC2F5)6] and Hexaethylenoxide Containing Mesogenic Dimers

open access: yesAdvanced Materials, EarlyView.
Associating a red‐NIR phosphorescent octahedral hexanuclear molybdenum cluster compound with hexaethyleneoxide chains bearing mesogenic units on both ends leads to an emissive hybrid liquid crystal showing mesomorphism on a very unusual temperature range down to −25°C.
Killiann Heinz   +11 more
wiley   +1 more source

Trions as Fundamental Species in Chemically Doped Polymer Semiconductors

open access: yesAdvanced Materials, EarlyView.
This work shows that exciton–charge carrier coupling in doped polymer semiconductors gives rise to multi‐particle states, including trions—quasiparticles consisting of two holes and one electron under p‐doping—and bound exciton‐hole pairs, as identified through spectroscopic and theoretical analysis.
Hongmo Li   +23 more
wiley   +1 more source

Laplace‐Pressure‐Stabilized Rutile Solid‐Solution Catalysts for Acidic Water Oxidation: Enabling DSA‐Inspired Compositions

open access: yesAdvanced Materials, EarlyView.
The miscibility of foreign elements in rutile‐type IrO2 and SnO2 is greatly enhanced under high Laplace pressure, where their crystal size is reduced to the nanoscale. This enhancement leads to the successful synthesis of DSA‐composition solid‐solution nanocatalysts with notable durability during the acidic OER in water electrolysis.
Chang Hyun Park   +7 more
wiley   +1 more source

Organic–Inorganic Hybrid Hole‐Selective Layer Interface Engineering for Enhanced Photoelectrochemical Water Oxidation on Bismuth Vanadate Photoanodes

open access: yesAdvanced Materials, EarlyView.
In this research the [4‐(3,6‐dimethyl‐9H‐carbazol‐9‐yl)butyl] phosphonic acid (Me‐4PACz) self‐assembled monolayers (SAMs) to bond with NiOx is first designed to be the organic‐inorganic hybrid hole‐selective layers, which promotes the BiVO4 photoanodes photoelectrochemical water splitting performance with 6.9 mA cm−2 photocurrent at 1.23 VRHE and at ...
Kaige Tian   +10 more
wiley   +1 more source

Comparative Analysis of Work Function Measurement Techniques Based on Scanning Probe Microscopy

open access: yesAdvanced Materials, EarlyView.
Non‐contact scanning probe microscopy visualizes the surface topography based on surface electronic properties. The tunneling current, which defines the geometry of the tunnel–junction, has to overcome the effective surface work function barrier to reach the probe from the surface.
Daryoush Nosraty Alamdary   +2 more
wiley   +1 more source

Reconfigurable Ferroelectric‐Like Two‐Dimensional Electron Gas at Room Temperature

open access: yesAdvanced Materials, EarlyView.
We demonstrate the realization of a novel ferroelectric‐like two‐dimensional electron gas (2DEG) based on the epitaxial interface between SrO‐terminate SrTiO3 and ferroeletric KNb0.5Na0.5O3${\rm KNb}_{0.5}{\rm Na}_{0.5}{\rm O}_3$ thin films. We show nonvolatile control of the transport properties enabling spatially reconfigurable devices in which ...
Martando Rath   +16 more
wiley   +1 more source

Angstrom‐Scale Confined Ion Sieve and Accelerator for Efficient Aqueous Zinc Batteries

open access: yesAdvanced Materials, EarlyView.
An angstrom‐scale confined ion accelerator strategy is proposed for ultra‐stable aqueous Zn anodes. Selective and precise transport of hydrated Zn(H2O)62+, Zn2+ cations, H2O molecules, and SO42− anions is achieved by in‐plane atomic Ti vacancies and angstrom‐scale interlayer free spacing within the Ti0.87O2 interfacial layer, leading to homogeneous Zn ...
Xing Peng   +16 more
wiley   +1 more source

Hydrophobic MFI‐Type Zeolites via Alkali‐Cation‐Induced Defect Healing: Implications for Adsorbent and Catalyst Design

open access: yesAdvanced Materials, EarlyView.
Sub‐stoichiometric amounts of Na+ or K+ enhance defect healing during Silicalite‐1 (MFI) and TS‐1 calcination by promoting Si–O–Si annealing and healing framework vacancies. The resulting defect‐free zeolites are more hydrophobic and show improved butanol/water separation and improved activity and selectivity in the epoxidation of 1‐hexene, offering a ...
Christos Kanteler   +14 more
wiley   +1 more source

Descriptive review of junior OB/GYN physicians' work task financial compensation in German hospitals. [PDF]

open access: yesJ Occup Med Toxicol, 2019
Brüggmann D   +8 more
europepmc   +1 more source

Sustainable and Multifunctional Natural Macromolecular Polymers for Aqueous Zn Metal Batteries

open access: yesAdvanced Materials, EarlyView.
We comprehensively review the structure‐function relationships and regulatory mechanism of natural macromolecular polymers in stabilizing zinc anodes at the microscopic and mesoscopic scales. The interactions among polymer structures, optimization strategies, and regulatory mechanisms are discussed systematically summarizing recent related research ...
Yunuo Shi   +13 more
wiley   +1 more source

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