Results 211 to 220 of about 21,289 (291)
Boron-based fire retardancy for natural polymeric materials. [PDF]
Wang X, Shi SQ.
europepmc +1 more source
ABSTRACT The development of synthetic procedures for preparing metal nanoparticles with controlled size using sunlight opens new avenues toward more sustainable methods with lower energy consumption. Herein, we propose the use of double‐vacancy halide perovskites as precursors for engineering highly crystalline and small platinum nanoparticles (< 3 nm)
Kevin Mego +4 more
wiley +1 more source
Alkali‐Metal Base Catalyzed Electrocyclization of Isoprene Derivatives
Simple and abundant alkali‐metal base catalysis in combination with Lewis basic polyamines enables the electrocyclization of isoprene‐derived trienes to cycloheptadienes under neat conditions. Mechanistic insight supported by DFT guides a scalable route to seven‐membered carbocycles which, after reduction, give saturated cycloalkanes relevant as ...
Mikaël Le Roch +3 more
wiley +1 more source
Catalyst‐Free Cyanation of Arenes by Acetonitrile in a Plasma–Liquid Microreactor
An original approach of arylnitrile synthesis was developed by generating an argon plasma in contact with solutions of arene in acetonitrile within a gas‐liquid microreactor. Plasma activation of acetonitrile generated cyano radicals, enabling a catalyst‐free C‐H cyanation of arenes.
Pierre Dedieu +4 more
wiley +1 more source
Analyzing the coupling characteristics of real-time key parameters in the thermal runaway of NCM523 batteries. [PDF]
Zhong C +7 more
europepmc +1 more source
A fully noble‐metal‐free photocatalytic system that couples cobaloxime catalysis with Cu photosensitizer for HAT‐driven acetylene‐to‐ethylene conversion is reported. ABSTRACT The purification of ethylene streams from acetylene impurities remains a key industrial challenge, for which light‐powered strategies are emerging as sustainable alternatives to ...
Anna Fortunato +5 more
wiley +1 more source
Quinolin‐4‐ones were converted to chloroquinolinium salts, allowing formation of axially chiral aminoquinolinium salts via an enantioretentive SNAr reaction with a variety of amine nucleophiles. The salts have a high rotational barrier, with a racemization half‐life of ∼1000s of years.
Darren Holmes +5 more
wiley +1 more source
A Sub-Milliwatt Graphene-Based Thermal Conductivity Detector for On-Site Gas Analysis. [PDF]
Sium FS +7 more
europepmc +1 more source
Azidophosphonamido Rhodium(I) and Iridium(I) Complexes: Synthesis, Properties, and Linkage Isomerism
A family of azidophosphonamido ligands and their corresponding rhodium(I) and iridium(I) complexes were synthesized. The rich reaction chemistry of these species revealed unusual linkage isomerization processes and bonding motifs. M = Rh, Ir; Mes = 2,4,6‐Me3C6H2. ABSTRACT A series of azidophosphonamido rhodium(I) and iridium(I) complexes ([iPr2P(N3R)NR]
Emily L. Trew +3 more
wiley +1 more source

