Results 91 to 100 of about 3,382 (273)

Dynamic‐FLPs Enabled by Orbital Hybridization Tuning: Boosting 100% CO Selectivity for Dilute CO2‐to‐CO Conversion

Carbon Energy, EarlyView.
This study, for the first time, constructs photostructured dynamic frustrated Lewis pairs (DFLPs) via a p‐p orbital hybridization regulation strategy, achieving the 100% reduction of low‐concentration CO₂ to CO and breaking the stability‐activity trade‐off.
Xiao‐hong Wang, Wen‐qing Gao, Jin‐li Liu, Yi‐lei Li, Hui‐ying Mu, Ying Liu, Fa‐tang Li   +6 more
wiley   +1 more source

Thermodynamic functions and parameters of sorption from flue gases (CO2,SOx,NOx) by Khekordzula clinoptilolite

Chemical Thermodynamics and Thermal Analysis
Generation during the production process and emissions into the atmosphere with flue gases (CO2,SOx,NOx) cause the “greenhouse effect” and the problem of global warming. Despite the existing practice of using zeolite as an adsorbent for a number of gases
Rajden Skhvitaridze, Irakli Giorgadze, Teimuraz Cheishvili, Vladimer Gordeladze, Givi Loladze, Nino Mukhadgverdeli, Manana Kekelidze, Akaki Skhvitaridze   +7 more
doaj   +1 more source

Ultrafast Synthesis of a Non‐Noble FeCoNiCrZn Multi‐Element Alloy Electrocatalyst for Alkaline Oxygen Evolution Reaction

Carbon Energy, EarlyView.
A nanoporous carbon‐coated FeCoNiCrZn multi‐element alloy on carbon cloth (FeCoNiCrZn‐C@CC) is fabricated by ultrafast pulsed laser irradiation. It has excellent OER performance, achieving an overpotential of only 233 mV at 10 mA cm−2 and remarkable stability for 94 h at 250 mA cm−2, which is due to multiple factors.
Yu Liang, Yu Lu, Jianghong Zhang, Zichen Xu, Mingzhen Xiu, Jiuyang Xia, Junrong Yue, Yifan Li, Yi Cui, Yingpeng Xie, Yizhong Huang, Guangwen Xu, Zhong‐Shuai Wu   +12 more
wiley   +1 more source

Fe–Mn Heterojunction Modulated Electronic Environment for Enhanced CO2 Capture and In Situ Conversion

Carbon Energy, EarlyView.
Fe–Mn heterojunctions in CaO‐based dual‐functional materials create a built‐in electric field that drives electron transfer. This process generates oxygen vacancies and facilitates CO2 activation, achieving superior conversion. Waste‐derived Fe/Ca oxides enable low‐cost, thermally stable materials, offering a strategy for sustainable carbon capture and
Han Zhang, Ziyan Yang, Xiaohang Huang, Junxian Han, Yujing Zhang, Yuqi Zhang, Fumei Wang, Lina Liu, Zhikun Zhang   +8 more
wiley   +1 more source

Photochemistry of Aromatic N‐Oxides in Water Probed by Time‐Resolved X‐ray Absorption Spectroscopy

Chemistry – A European Journal, EarlyView.
Time‐resolved XAS at the nitrogen and oxygen K‐edges is applied to the photorearrangement of two N‐oxides in water. Pyridine N‐oxide rapidly forms the oxaziridine isomer. Pyridazine N‐oxide undergoes ring opening to the diazo compound, without any evidence of intermediates.
Maximilian Paradiz Domínguez, Robby Büchner, Mattis Fondell, Albert M. Brouwer   +3 more
wiley   +1 more source

Collision Milling of Oil Shale Ash as Constituent Pretreatment in Concrete 3D Printing

Infrastructures
Concrete is an essential construction material, and infrastructures, such as bridges, tunnels, and power plants, consume large quantities of it. Future infrastructure demands and sustainability issues necessitate the adoption of non-conventional ...
Lucija Hanžič, Mateja Štefančič, Katarina Šter, Vesna Zalar Serjun, Māris Šinka, Alise Sapata, Genādijs Šahmenko, Evaldas Šerelis, Baiba Migliniece, Lidija Korat Bensa   +9 more
doaj   +1 more source

In situ Generation of Fluoride Catalysts for CO2‐to‐Formic Acid Conversion With Silicon Reducing Agent

Chemistry – A European Journal, EarlyView.
Reductive conversion of CO2 to formic acid with waste silicon reducing agent catalyzed by in situ generation of active fluoride species from a tertiary amine, protonic acid, and simple inorganic fluoride salt, such as KF and NaF. ABSTRACT The activation and catalytic reduction of carbon dioxide (CO2) using silicon‐based reducing agents is an important ...
S. M. A. Hakim Siddiki, Yusuke Tanimura, Mariko Honda, Shingo Hasegawa, Kazuo Namba, Yuichi Manaka, Ken Motokura   +6 more
wiley   +1 more source

Global and Detailed Calculation of Tube Wall Temperature in a Process Furnace Steam Superheater

Chemie Ingenieur Technik, EarlyView.
This study presents a comparison between an iterative global model and multiple approaches to a new non‐iterative model with the purpose of predicting tube wall temperature of a superheater. The results show that the non‐iterative method achieves sufficient accuracy while improving the prediction of local temperature distribution and better ...
Anežka Michálková, Zdeněk Jegla
wiley   +1 more source

Matching Heat Pump Configurations and Process Parameters for Cost‐Minimal Heat‐Integrated CO2 Capturing Process

Chemie Ingenieur Technik, EarlyView.
In a CO2 absorption process, it is investigated whether the adjustment of operating parameters facilitates the integration of different closed heat pump cycles considering various refrigerants. The influence of different integration concepts and electricity prices are investigated by means of resulting total annual costs.
Johannes Wloch, Marcus Grünewald, Julia Riese   +2 more
wiley   +1 more source

Random forest regression for catalyst performance prediction and validation of tri‐reforming of methane (TRM)

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract Carbon dioxide‐reduced hydrogen can be synthesized through various methods such as dry‐reforming (DRM), steam reforming (SMR), and partial oxidation (POX). Tri‐reforming of methane (TRM) is a promising technology which combines all the above‐mentioned processes for the simultaneous production of hydrogen and syngas with high energy efficiency.
Paulo A. L. de Souza, Raja Muhammad Afzal, Felipe Gomes Camacho, Nader Mahinpey   +3 more
wiley   +1 more source