Results 91 to 100 of about 4,019 (241)

Advances in conjugated porous polymers via high internal phase emulsion templating

open access: yesPolymer International, EarlyView.
This mini‐review highlights the design, synthesis and potential applications of π‐conjugated polyHIPEs, emphasizing their unique hierarchical structure and tunable properties. The work outlines innovative synthetic strategies and explores their promising roles in photocatalysis and environmental remediation, paving the way for future advancements in ...
Julie‐Lisa Malaval   +4 more
wiley   +1 more source

Chromium(III)-Catalyzed Desymmetrization of meso-Epoxides via Remote Stereocontrol: Synthesis of Chiral Fluorenes Bearing All-Carbon Quaternary Stereocenters

open access: yes
An asymmetric desymmetrization of fluorene-derived meso-epoxides is disclosed for the construction of chiral fluorenes bearing an all-carbon quaternary stereocenter at C9.
Wengang Guo (3773317)   +4 more
core   +1 more source

Brönsted Acid-Mediated Intramolecular Cyclization of Biaryl Triazenes for the Synthesis of Fluorenes and 9,10-Dihydro-Phenanthrenes

open access: yes, 2016
The efficient synthesis of fluorenes from biaryl triazenes is successfully developed. Up to 27 examples of biaryl triazenes are converted into their corresponding fluorene derivatives in the presence of CF3COOH (4.0 equiv).
Xin Xu (11989)   +6 more
core   +1 more source

MXene‐Based Flexible Memory and Neuromorphic Devices

open access: yesSmall, EarlyView.
The unique two‐dimensional structure, excellent electrical conductivity, and diverse surface groups of MXenes have garnered significant attention. Coupled with their exceptional flexibility, MXene‐based devices hold immense potential for flexible memory and neuromorphic systems. This review comprehensively discusses the fundamentals of flexible devices,
Yan Li   +13 more
wiley   +1 more source

Cyclo-oligomerization of 6,12-Diethynyl Indeno[1,2‑b]fluorenes via Diradical Intermediates

open access: yes, 2015
Indeno­[1,2-b]­fluorene derivatives with trimethylsilylethynyl substituents at the 6- and 12-positions were found to undergo cyclo-dimerization, cyclo-trimerization, and higher oligomerizations at room temperature.
Xiangyu Fu (1479364)   +1 more
core   +2 more sources

Non‐Covalent PL, CD, and CPL Activation of Linear Aromatic Oligomers within Axially Chiral Aromatic Capsules

open access: yesAngewandte Chemie, Volume 138, Issue 42, 12 October 2026.
Linear aromatic oligomers display intense photoluminescence (PL), circular dichroism (CD), and circularly polarized luminescence (CPL) properties upon non‐covalent encapsulation by axially‐chiral aromatic capsules under ambient aqueous conditions.
Yoshihisa Hashimoto   +4 more
wiley   +2 more sources

Cooperative Regulation of Defect‐Mediated Molecular Recognition With Single‐Walled Carbon Nanotubes

open access: yesSmall, EarlyView.
Defect‐mediated sensing in SWCNTs arises from the cooperative interplay of defect characteristics, density, heterogeneity, analyte properties, corona composition, and environment. Understanding these interconnected variables enables tunable fluorescence modulation, selective molecular recognition, ratiometric sensing, and sensitive detection in complex
Srestha Basu, Gili Bisker
wiley   +1 more source

Synthesis of 9-Alkylidene-9H-fluorenes by a Novel, Palladium-Catalyzed Cascade Reaction of Aryl Halides and 1-Aryl-1-alkynes

open access: yes, 2016
In the presence of a palladium catalyst and NaOAc, aryl iodides react with 1-aryl-1-alkynes to afford 9-alkylidene-9H-fluorenes in good yields. The products from this reaction are highly dependent on the base employed. This process appears to involve (1)
Richard C. Larock (1353099)   +1 more
core   +1 more source

Unraveling the effect of topological structures of B/N‐doped conjugated macrocycles on spectral properties: A computational study

open access: yesSmart Molecules, EarlyView.
Herein, we constructed a series of fully B‐doped, fully N‐doped and hybrid B/N‐doped conjugated macrocycles considering three key topological factors. At a fixed ring size, the spectra initially redshift then blueshift with varying B/N ratio, while ring size exhibits negligible impact on spectra.
Wen‐Yu Guo   +4 more
wiley   +1 more source

Oxaziridines: Versatile Reagents in Modern Organic Synthesis

open access: yesThe Chemical Record, EarlyView.
Being capable of transferring an O atom and N‐group/atom, oxaziridines are considered multitasking agents. These are employed for diverse organic transformations, such as epoxidation of olefins, α‐ and γ‐hydroxylation/amination of carbonyl compounds, oxidation of sulfides, [3+2]cycloaddition with unsaturated systems.
Ajeet Chandra   +2 more
wiley   +1 more source

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