Results 11 to 20 of about 281,084 (357)
A rapid access to aliphatic sulfonyl fluorides
Sulfonyl fluorides are important probes in chemical biology and molecular pharmacology. Here, the authors report a mild visible light-mediated decarboxylative fluorosulfonylethylation for the synthesis of aliphatic sulfonyl fluorides from a wide range of
Ruting Xu+4 more
doaj +2 more sources
Nickel-Catalyzed Decarbonylative Stannylation of Acyl Fluorides under Ligand-Free Conditions
Nickel-catalyzed decarbonylative stannylation of acyl fluorides under ligand-free conditions was disclosed. A variety of aromatic acyl fluorides are capable of reacting with silylstannanes in the presence of cesium fluoride.
Xiu Wang+4 more
doaj +2 more sources
Aroyl Fluorides as Bifunctional Reagents for Dearomatizing Fluoroaroylation of Benzofurans
The 2,3-dihydrobenzofuran scaffold is widely found in natural products and biologically active compounds. Herein, dearomatizing 2,3-fluoroaroylation of benzofurans with aroyl fluorides as bifunctional reagents to access 2,3-difunctionalized ...
Xiaoye Yu+3 more
semanticscholar +1 more source
Probing Dynamic Self‐Reconstruction on Perovskite Fluorides toward Ultrafast Oxygen Evolution
Exploring low cost, highly active, and durable electrocatalysts for oxygen evolution reaction (OER) is of prime importance to boost energy conversion efficiency.
Jing Zhang+6 more
semanticscholar +1 more source
Hitherto, there are almost no reports on the complete reconstruction in hydrogen evolution reaction (HER). Herein, the authors develop a new type of reconfigurable fluoride (such as CoF2) pre‐catalysts, with ultra‐fast and in‐depth self‐reconstruction ...
Pengxia Ji+10 more
semanticscholar +1 more source
The Emerging Applications of Sulfur(VI) Fluorides in Catalysis
The past decade has witnessed remarkable growth of catalytic transformations in organic sulfur(VI) fluoride chemistry. This Perspective concentrates exclusively on foundational examples that utilize catalytic strategies to synthesize and react S(VI ...
semanticscholar +1 more source
High-Entropy Perovskite Fluorides: A New Platform for Oxygen Evolution Catalysis.
High-entropy perovskite fluorides (HEPFs) have great poten-tial in electrocatalysis that has not been realized because of the limitation of a high-temperature synthetic route and the limited understanding of high-entropy materials.
Tao Wang+4 more
semanticscholar +1 more source
Alkyl fluorides modulate the conformation, lipophilicity, metabolic stability, and p K a of compounds containing aliphatic motifs and, therefore, have been valuable for medicinal chemistry.
T. W. Butcher, W. Amberg, J. Hartwig
semanticscholar +1 more source
Luminescent properties of Bax Mg(2−x)F4:W ceramics
Ceramics based on alkaline earth metal fluorides activated by tungsten has been obtained by radiation synthesis. The synthesis was realized by direct action on the mixture with an activator of a powerful flow of high-energy electrons without the use of ...
T.A. Koketai+6 more
doaj +1 more source
The first examples of layered hybrid iron fluorides are reported. In the reactions carried out, the chain compound (H2pipz)FeF5·H2O always occurs as the major phase, with the layered compounds, (H2pipz)3Fe4F18·2H2O and (H2pipz)2Fe3F13·H2O, being isolated
Teng Li, Philip Lightfoot
doaj +1 more source