Results 21 to 30 of about 21,209 (311)

Rh-Catalyzed Highly Enantioselective Synthesis of Aliphatic Sulfonyl Fluorides

open access: yesiScience, 2019
Summary: Rh-catalyzed, highly enantioselective (up to 99.8% ee) synthesis of aliphatic sulfonyl fluorides was accomplished. This protocol provides a portal to a class of novel 2-aryl substituted chiral sulfonyl fluorides, which are otherwise extremely ...
Balakrishna Moku   +6 more
doaj   +1 more source

Deoxyfluorination of acyl fluorides to trifluoromethyl compounds by FLUOLEAD®/Olah’s reagent under solvent-free conditions

open access: yesBeilstein Journal of Organic Chemistry, 2020
A new protocol enabling the formation of trifluoromethyl compounds from acyl fluorides has been developed. The combination of FLUOLEAD® and Olah’s reagent in solvent-free conditions at 70 °C initiated the significant deoxyfluorination of the acyl ...
Yumeng Liang   +4 more
doaj   +1 more source

Luminescent properties of Bax Mg(2−x)F4:W ceramics

open access: yesEurasian Journal of Physics and Functional Materials, 2023
Ceramics based on alkaline earth metal fluorides activated by tungsten has been obtained by radiation synthesis. The synthesis was realized by direct action on the mixture with an activator of a powerful flow of high-energy electrons without the use of ...
T.A. Koketai   +6 more
doaj   +1 more source

Synthesis of Highly Enantioenriched Sulfonimidoyl Fluorides and Sulfonimidamides by Stereospecific SuFEx Reaction

open access: yes, 2020
Sulfonimidamides present exciting opportunities as chiral isosteres of sulfonamides, with potential for additional directional interactions. Here we present the first modular enantioselective synthesis of sulfonimidamides, including the first ...
Andrew J. P., White   +5 more
core   +1 more source

Biocatalytic asymmetric construction of secondary and tertiary fluorides from β-fluoro-α-ketoacids

open access: yes, 2021
Fluorine is a critical element for the design of bioactive compounds, but its incorporation with high regio- and stereoselectivity using environmentally friendly reagents and catalysts remains an area of development. Stereogenic tertiary fluorides pose
Jason, Fang   +2 more
core   +1 more source

Layered Hybrid iron Fluorides [PDF]

open access: yes, 2022
The first examples of layered hybrid iron fluorides are reported. In the reactions carried out, the chain compound (H2pipz)FeF5·H2O always occurs as the major phase, with the layered compounds, (H2pipz)3Fe4F18·2H2O and (H2pipz)2Fe3F13 ...
Teng Li   +3 more
core   +1 more source

Improving oral health of children in four Balkan countries: A qualitative study among health professionals

open access: yesFrontiers in Oral Health, 2023
Data from the WHO show that the oral health situation for children in the Balkan region of Europe is poor. This study aims to identify obstacles that prevent the implementation of an effective oral health program for children in the Balkan area.
Enes Karamehmedovic   +5 more
doaj   +1 more source

XAFS analyses of molten metal fluorides [PDF]

open access: yes, 2009
X-ray absorption fine structure studies of molten metal fluorides containing the materials related to nuclear engineering are intensively summarized. By using XAFS spectra data of divalent and trivalent cation metal fluorides in molten state which have ...
Watanabe, Sou   +4 more
core   +1 more source

Buffering Capacity and Effects of Sodium Hexametaphosphate Nanoparticles and Fluoride on the Inorganic Components of Cariogenic-Related Biofilms In Vitro

open access: yesAntibiotics, 2022
Despite the remarkable effects of sodium hexametaphosphate nanoparticles (HMPnano) on dental enamel de-/re-mineralization processes, information on the effects of these nanoparticles on biofilms is scarce. This study assessed the effects of HMPnano, with
Caio Sampaio   +7 more
doaj   +1 more source

Diversity Oriented Clicking: Synthesis of beta-Substituted Alkenyl Sulfonyl Fluorides as Covalent Human Neutrophil Elastase Inhibitors

open access: yes, 2022
Diversity Oriented Clicking (DOC) is a discovery method geared towards the rapid synthesis of functional libraries. It combines the best attributes of both classical and modern click chemistries. DOC strategies center upon the chemical diversification of
Yunfei, Cheng   +12 more
core   +1 more source

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