Electrocatalytic Formate Oxidation by Cobalt-Phosphine Complexes [PDF]
, 2023 We report a family of cobalt complexes based on bidentate phosphine ligands with two, one, or zero pendent amine groups in the ligand backbone. The pendent amine complexes are active electrocatalysts for the formate oxidation reaction, generating CO2 ...
Andrew W., Cook +4 more
core +2 more sources
Molecules, 2023 A complex [Zn(bpy)(acr)2]·H2O (1) was converted in a DMF medium (DMF = N,N′-dimethylformamide) into a coordination polymer [Zn(bpy)(acr)(HCOO)]n (1a) (bpy = 2,2′-bipyridine, and Hacr = acrylic acid), and the species was fully characterized through a ...
Gina Vasile Scăețeanu +3 more
doaj +1 more source
Frontiers in Microbiology, 2022 The sensitivity of anaerobic ammonium-oxidizing (anammox) bacteria to environmental fluctuations is a frequent cause of reactor malfunctions. It was hypothesized that the addition of formate and folate would have a stimulating effect on anammox bacteria,
Anna Kallistova +12 more
doaj +1 more source
Photoinduced Hydrocarboxylation via Thiol-Catalyzed Delivery of Formate Across Alkenes [PDF]
, 2021 Herein we disclose a new photochemical process to prepare carboxylic acids from formate salts and alkenes. This redox-neutral hydrocarboxylation proceeds in high yields across diverse functionalized alkene substrates with excellent regioselectivity. This
Zachary, Wickens, Sara, Alektiar
core +2 more sources
Elucidating the role of formate on cancer cell invasion [PDF]
, 2022 Metabolic rewiring is essential to enable cancer onset and progression. One important metabolic pathway that is often hijacked by cancer cells is the one-carbon (1C) cycle, in which the third carbon of serine is oxidized to formate.
DELBROUCK, Catherine Anne Lucie
core +1 more source
Programmable Guest-Induced 5-Phase-Transition Topological Reconstructions of Cobalt Formate Metal-Organic Frameworks. [PDF]
Adv Sci (Weinh)A reversible five‐phase topological cycle is achieved in a minimalist cobalt formate metal–organic framework. The amorphous phase functions as a programmable reactive hub, selectively reconstructing into four distinct crystalline architectures through cationic templates, humidity, or CO2.
Tao Z +6 more
europepmc +2 more sources
Genomic potential and physiological characteristics of C1 metabolism in novel acetogenic bacteria
Frontiers in Microbiology, 2023 Acetogenic bacteria can utilize C1 compounds, such as carbon monoxide (CO), formate, and methanol, via the Wood-Ljungdahl pathway (WLP) to produce biofuels and biochemicals.
Jihyun Yu +17 more
doaj +1 more source
Biochemical Evidence for formate transfer in syntrophic propionate oxidizing cocultures of Syntrophobacter fumaroxidans and Methanospirillum hungatei [PDF]
, 2002 The hydrogenase and formate dehydrogenase levels in Syntrophobacter fumaroxidans and Methanospirillum hungatei were studied in syntrophic propionate-oxidizing cultures and compared to the levels in axenic cultures of both organisms.
Bok, F.A.M., de +3 more
core +1 more source
A Transfer Hydrogenation Approach to Activity-Based Sensing of Formate in Living Cells [PDF]
, 2023 Formate is a major reactive carbon species in one-carbon metabolism, where it serves as an endogenous precursor for amino acid and nucleic acid biosynthesis and a cellular source of NAD(P)H.
Vanha, Pham +5 more
core +2 more sources
Microbial Resource Management for Ex Situ Biomethanation of Hydrogen at Alkaline pH
Microorganisms, 2020 Biomethanation is a promising solution to convert H2 (produced from surplus electricity) and CO2 to CH4 by using hydrogenotrophic methanogens. In ex situ biomethanation with mixed cultures, homoacetogens and methanogens compete for H2/CO2.
Washington Logroño +5 more
doaj +1 more source