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On the Gas-Phase Interactions of Alkyl and Phenyl Formates with Water: Ion–Molecule Reactions with Proton-Bound Water Clusters [PDF]
Molecules, 2023 Ion–molecule reactions between the neutral ethyl- (EF), isopropyl- (IF), t-butyl- (TF) and phenyl formate (PF) and proton-bound water clusters W2H+ and W3H+ (W = H2O) showed that the major reaction product is water loss from the initial encounter complex,
Malick Diedhiou, Paul M. Mayer
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Achievements and challenges in deciphering heterogeneous catalytic reaction mechanisms using operando infrared spectroscopies [PDF]
Nature CommunicationsIn situ / operando infrared spectroscopy is commonly used to investigate heterogeneous catalytic reactions. Adsorbates, such as carbonyl and formates, present under reaction conditions can be monitored and quantitative infrared techniques enable ...
Frederic C. Meunier, Alexandre Goguet
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Generation of Formates Following 20 kHz Sonication of DSPE-mPEG2000 PEGylated Phospholipid Micelles [PDF]
PharmaceuticsBackground: Previous research has demonstrated that 20 kHz probe or 37 kHz bath sonication of poloxamers comprising polypropylene glycol (PPG) and polyethylene glycol (PEG) blocks can generate degradation byproducts that are toxic to mammalian cells and ...
Perouza Parsamian, Paul Pantano
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Palladium-Catalyzed Esterification of Aryl Fluorosulfates with Aryl Formates [PDF]
MoleculesAn efficient palladium-catalyzed carbonylation of aryl fluorosulfates with aryl formates for the facile synthesis of esters was developed. The cross-coupling reactions proceeded effectively in the presence of a palladium catalyst, phosphine ligand, and ...
Xue Chen +8 more
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Starch Formates: Synthesis and Modification
Molecules, 2021 Starch can be efficiently converted into the corresponding formates homogeneously using N-formyl imidazole obtained by the reaction of 1,1′-carbonyldiimidazole and formic acid in dimethyl sulfoxide as a solvent.
Sascha Blohm, Thomas Heinze, Haisong Qi
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Glycosyl Formates: Glycosylations with Neighboring-Group Participation
Molecules, 2022 Protected 2-O-benzyolated glycosyl formates were synthesized in one-step from the corresponding orthoester using formic acid as the sole reagent.
Liang Yang, Christian Marcus Pedersen
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Inorganics, 2023 The increase in anthropogenic CO2 concentrations and associated environmental issues have demanded the development of technologies for CO2 utilization.
Tolganay Andizhanova +2 more
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The formation of formates: a review of metal formates on heritage objects
Heritage Science, 2021 Metal formates sometimes occur as degradation products on heritage objects due to the use of wood products or other sources of formic acid and formaldehyde.
Gerhard Eggert, Andrea Fischer
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Thermal Decomposition of [AH][M(HCOO)3] Perovskite-Like Formates
Solids, 2021 A systematic study of the thermal decomposition of hybrid perovskites of formula [AH][M(HCOO)3] under inert atmosphere was performed by means of thermogravimetry and simultaneous infrared spectroscopy of the evolved gases. The influence of: (i) the metal
Lilián Claudia Gómez-Aguirre +5 more
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Crystals, 2023 In order to understand the phenomenon of negative linear compressibility (NLC) in organic crystals, it is necessary to investigate not only the structural features but also the electronic changes taking place under external hydrostatic pressure.
Yury V. Matveychuk +4 more
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