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Magnetic Alumina for Chromium Ion Remediation: Isotherm Analysis and Kinetic Modeling. [PDF]

open access: yesACS Omega
Md Hanafiah SF   +3 more
europepmc   +1 more source
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ON THE BASIS FOR THE FREUNDLICH ADSORPTION ISOTHERM

Chemical Engineering Communications, 1990
Abstract The theoretical underpinnings of the Freundlich adsorption isotherm, an often useful empiricism, are discussed. It is shown that the Freundlich expression does not originate from a true exponential distribution of energies of adsorption for the adsorption sites.
David O Cooney
exaly   +2 more sources

Freundlich's Isotherm Extended by Statistical Mechanics

Journal of Colloid and Interface Science, 1997
In this paper we obtain an asymptotic development compatible with Freundlich's isotherm, theta = KCm. That expression was derived underlying the theory of heterogeneous surface. We assume the distribution function of adsorption sites to be in the exponential form and the sites to follow the Langmuir energy homogeneous isotherm.
Evaldo JOSÉ Corat
exaly   +3 more sources

Statistical Mechanical Study on the Freundlich Isotherm Equation

Journal of Colloid and Interface Science, 1998
The Freundlich isotherm equation, in the form of theta = KP1/n, was derived by treating the model with the ensemble theory in statistical mechanics as a theoretical tool, the model being set up for the adsorption system with emphasis on two factors, namely the lateral interaction between the adsorbed molecules and the energetic surface heterogeneity ...
exaly   +3 more sources

The Influence of the Temperature on the Parameters of Extended Freundlich's Isotherm

Journal of Colloid and Interface Science, 1998
Abstract In this paper the expression for adsorption isotherm expressed by an asymptotic development, the extended Freundlich's isotherm, was applied to the study and interpretation of energetic heterogeneity. This expression presents the relative monolayer coverage of the entire surface as a dependence on adsorbate pressure (or concentration) and on
Evaldo JOSÉ Corat
exaly   +2 more sources

Predicting Freundlich adsorption isotherm of atrazine on Japanese soils

Soil Science and Plant Nutrition, 2001
Abstract It was possible to predict the amounts of atrazine adsorption on Japanese soils by deriving predicting equations from the value of the initial concentration of atrazine applied to the soils containing less than 70 g kg-1 carbon. The equations predicted the values of Freundlich isotherm coefficients, log K F and 1/n.
Koyo Yonebayashi, Takashi Kosaki
exaly   +2 more sources

Application of the Freundlich adsorption isotherm in the characterization of molecularly imprinted polymers

Analytica Chimica Acta, 2001
The binding isotherm for a polymer molecularly imprinted with ethyl adenine-9-acetate was observed to obey the common Freundlich isotherm. To test the generality of the Freundlich isotherm with respect to molecularly imprinted polymers (MIPs), a survey of systems from the literature was conducted, revealing that the Freundlich isotherm gives a good ...
Sarah C Baxter, Ken D Shimizu
exaly   +2 more sources

The Derivation of Freundlich Adsorption Isotherm

University Chemistry, 2015
Shi Jibin, Liu Guojie
exaly   +2 more sources

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