Results 281 to 290 of about 265,527 (339)

Gel‐Gel Interface Engineering for the Synthesis of Anisotropic Hydrogels with Designable Polymer Orientations

open access: yesAdvanced Materials, EarlyView.
This study reports that when a gel‐gel interface is intentionally introduced into a hydrogel via two‐step polymerization, the polymer networks near the interface spontaneously align perpendicular to it. By employing a photo‐initiator system to spatially control the gel‐gel interface, anisotropic hydrogels with programmable orientations of polymer ...
Tomohiro Takahashi   +2 more
wiley   +1 more source

High‐Performance Phototransistor Based on a 2D Polybenzimidazole Polymer

open access: yesAdvanced Materials, EarlyView.
A crystalline 2D polybenzimidazole polymer (2DPBI), incorporating a porphyrin‐based π‐system linked via 1,3‐diazole units, is synthesized on the water surface over large areas. The 2DPBI thin‐film exhibits high charge carrier mobility (≈240 cm2 V−1 s−1, measured by terahertz spectroscopy), strong photoresponse, and band‐like transport, enabling ...
Anupam Prasoon   +20 more
wiley   +1 more source

Accompanying Structural Transformations in Polarity Switching of Heavily Doped Conjugated Polymers

open access: yesAdvanced Materials, EarlyView.
The polarity switching of heavily doped p‐type conjugated polymers (CPs) toward environmentally stable electron‐rich thin films is demonstrated. Multiscale analyses, incorporating spectroscopic, electrochemical, and scattering techniques, reveal structural and chemical transformations induced by excessive doping with AuCl3.
Eunsol Ok   +11 more
wiley   +1 more source

Fluoroether Design Enables High‐Voltage All‐Solid‐State Lithium Metal Batteries

open access: yesAdvanced Materials, EarlyView.
A durable high‐voltage all‐solid‐state electrolyte is developed by incorporating a novel organic/inorganic hybrid porous component with a fluoroether design. Due to the weakened Li+ coordination structure, the proposed high‐voltage SSE exhibits durable antioxidation.
Yong Chen   +11 more
wiley   +1 more source

Ionically Conductive Elastic Polymer Binder for Ultrahigh Loading Electrode in High‐Energy‐Density Lithium Batteries

open access: yesAdvanced Materials, EarlyView.
An ionically conductive elastic polymer (ICEP) binder is introduced for fabricating ultrahigh mass‐loading NCM811 cathodes, offering enhanced elasticity, adhesion, and ionic conductivity for improved structural and interfacial stability. The ICEP‐based ultrahigh loading cathode delivers 377.6 Wh kgcell−1/1016.8 Wh Lcell−1 (including packaging) when ...
Dong‐Yeob Han   +9 more
wiley   +1 more source

Carbazole‐Based Thin Microporous Polymer Films for Photocatalytic Hydrogen Evolution

open access: yesAdvanced Materials, EarlyView.
Photocatalytic hydrogen evolution with electropolymerized microporous films enable a direct and scalable process for the production of industrial relevant amounts of hydrogen gas. For developing cost‐ and material‐effective devices it is beneficial to increase the accessible outer surface area via microstructuring and stacking of polymeric films ...
Veit Dippold   +10 more
wiley   +1 more source

A Light‐Driven Closed‐Loop Chemical Recycling System for Polypinacols

open access: yesAdvanced Materials, EarlyView.
This study presents a novel strategy for the photochemical closed‐loop recycling of hydroxyl‐rich polymers. Simple bis‐aldehyde precursors are employed to synthesize polypinacols via UV light irradiation. Subsequent depolymerization is achieved under visible light using a cerium‐based photocatalyst, enabling monomer recovery through selective cleavage ...
Ahsen Sare Yalin   +3 more
wiley   +1 more source

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