Fully conjugated azacorannulene dimer as large diaza[80]fullerene fragment [PDF]
Nature Communications, 2022 Heterofullerenes are an important synthetic target for organic chemists. Here, the authors demonstrate a fully conjugated azacorannulene dimer starting from a bifunctional polycyclic aromatic azomethine ylide, providing a powerful method for the bottom ...
Weifan Wang +4 more
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Fully conjugated ladder polymers. [PDF]
Chem Sci, 2017 Syntheses, properties and applications of fully conjugated ladder polymers are reviewed, together with an outlook to future opportunities and challenges.
Lee J +4 more
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Synthesis and Characterization of Fully Conjugated Ladder Naphthalene Bisimide Copolymers. [PDF]
Polymers (Basel), 2018 Fully conjugated ladder copolymers have attracted considerable attention due to their unique fused-ring structure and optoelectronic properties. In this study, two fully conjugated ladder naphthalene diimide (NDI) copolymers, P(NDI-CZL) and P(NDI-TTL) with imine-bridged structures are presented in high yields.
Liu F +6 more
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Synthesis and Properties of Fully-Conjugated Indacenedithiophenes. [PDF]
Chem Sci, 2014 The regioselective synthesis and optoelectronic characterization of four fully-conjugated, isomeric indacenedithiophenes are disclosed.
Young BS +5 more
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Fully Conjugated Tetraoxa[8]circulene-Based Porous Semiconducting Polymers. [PDF]
Angew Chem Int Ed Engl, 2022 AbstractTetraoxa[8]circulenes (TOCs) are a class of hetero[8]circulenes featuring a planar cyclooctatetraene core with a mixed aromatic/antiaromatic motif that governs their electronic properties. Polymeric TOCs (pTOCs) have been the subject of several computational simulations because they are predicted to be low‐band‐gap semiconductors, but they have
Fritz PW +5 more
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Fully‐Conjugated Covalent Organic Frameworks with Two Metal Sites for Oxygen Electrocatalysis and Zn–Air Battery [PDF]
Advanced Science, 2023 Covalent organic frameworks (COFs) are a promising alternative toward catalysis, due to the unique framework structure and the excellent chemical stability.
Jiawen Li +4 more
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A fully conjugated meso-boron-substituted porphyrinoid combining Lewis acidity with redox-switchable aromaticity [PDF]
Nature CommunicationsThe structural motif of porphyrin is relevant for many essential biological processes and has emerged as a versatile component of functional materials. Here, we introduce a thiophene-based porphyrinogen having electron-deficient boron atoms in all four ...
Manuel Buckel +8 more
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Templated bilayer self-assembly of fully conjugated π-expanded macrocyclic oligothiophenes complexed with fullerenes [PDF]
Nature Communications, 2017 Controlling the self-assembly of oligothiophene complexes that are used in multi-functional thin films can be challenging. Here the authors show a hierarchy of non-covalent interactions for robust self-assembly that orders Saturn-like complexes of ...
José D. Cojal González +2 more
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Optical properties of fully conjugated cyclo[n]thiophenes – An experimental and theoretical approach [PDF]
Beilstein Journal of Nanotechnology, 2011 Optical properties of two series of fully conjugated cyclo[n]thiophenes were analyzed experimentally and theoretically. The absorption spectra reveal a shift to higher wavelengths with increasing size of the cycles, which can be successfully described by
Elena Mena-Osteritz +4 more
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Single-atom platinum with asymmetric coordination environment on fully conjugated covalent organic framework for efficient electrocatalysis [PDF]
Nature CommunicationsTwo-dimensional (2D) covalent organic frameworks (COFs) and their derivatives have been widely applied as electrocatalysts owing to their unique nanoscale pore configurations, stable periodic structures, abundant coordination sites and high surface area.
Ziqi Zhang +12 more
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