Results 11 to 20 of about 633,575 (297)

Acid-Base Initiated Cyclization and Retrocyclization Reactions of Ethyl 2-(3-Acylselenoureido)benzoates, -thiophene-3-carboxylates and the Corresponding 2-(3-Acylisoselenoureido) Derivatives

open access: yesMolecules, 2000
Acid and base initiated cyclization and retrocyclization reactions of the selenoureas 1-6 and isoselenoureas 7-12 to fused 4H-1,3-selenazine and 1,2,3,4-tetrahydropyrimidine-4-one skeletons are reported.
Pavel Pazdera   +3 more
doaj   +1 more source

New Route to 3-Alkylthiazolo[3,2-a]benzimidazole Derivatives

open access: yesMolecules, 2005
3-Alkyl-thiazolo[3,2-a]benzimidazole derivatives are obtained in high yieldsvia the corresponding 4-alkyl-N-3-(2-aminophenyl)-thiazoline-2-thiones which are easilyprepared from 1,2-diaminobenzene, CS2 and halogenoketones.
Nicolas Vanthuyne   +4 more
doaj   +1 more source

Molecular perovskites as a new platform for designing advanced multi-component energetic crystals

open access: yesEnergetic Materials Frontiers, 2020
Molecular perovskite energetic crystals, as an emerging family of promising practicable energetic materials, have attracted increasing attentions in the past few years.
Wei-Xiong Zhang   +4 more
doaj   +1 more source

Synthesis of 5/6/5-fused tricyclic-cation-based cyclo-N5− salt with high density and heat of formation

open access: yesEnergetic Materials Frontiers, 2020
s: Pentazolate anion (cyclo-N5−) containing compounds have attracted wide interest in recent years. In this paper, to explore the fantastic chemistry of cyclo-N5−, a novel polyamino 5/6/5-fused tricyclic-cation-based cyclo-N5− salt, 2,3,5,6-tetraamino-9 ...
Sicheng Liao   +5 more
doaj   +1 more source

Systematic Study of Quaternary Ammonium Cations for Bromine Sequestering Application in High Energy Density Electrolytes for Hydrogen Bromine Redox Flow Batteries

open access: yesMolecules, 2021
Bromine complexing agents (BCAs) are used to reduce the vapor pressure of bromine in the aqueous electrolytes of bromine flow batteries. BCAs bind hazardous, volatile bromine by forming a second, heavy liquid fused salt.
Michael Küttinger   +4 more
doaj   +1 more source

Breathing Some New Life into an Old Topic: Chalcogen-Nitrogen π-Heterocycles as Electron Acceptors

open access: yesMolecules, 2013
Recent progress in the design, synthesis and characterization of chalcogen-nitrogen π-heterocycles, mostly 1,2,5-chalcogenadiazoles (chalcogen: S, Se and Te) and their fused derivatives, possessing positive electron affinity is discussed together with ...
Nina P. Gritsan   +3 more
doaj   +1 more source

A Study of Hot Corrosion of Fe-Cr Alloys Induced by a Thin Film of Fused (Na,K)2SO4 by Electrochemical Impedance Spectroscopy

open access: yesHigh Temperature Materials and Processes, 2013
To understand the hot corrosion mechanism of materials it is of significance to establish electrochemical measurements under a thin film of fused salts. In this paper, the hot corrosion behavior of Fe-Cr alloys containing 5, 10 and 25wt% Cr, respectively,
Liu S.N.   +4 more
doaj   +1 more source

Synthesis of the Benzo-fused Indolizidine Alkaloid Mimics

open access: yesBeilstein Journal of Organic Chemistry, 2007
A general synthesis of various benzo-fused indolizidine alkaloid mimics has been developed. The indolizidine derivatives 8 were prepared via heteroaryl Grignard addition to N-acylpyridinium salts followed by an intramolecular Heck cyclization.
Daniel L. Comins, Kazuhiro Higuchi
doaj   +1 more source

Copper-Catalyzed C–H Arylation of Fused-Pyrimidinone Derivatives Using Diaryliodonium Salts

open access: yesCatalysts, 2020
Copper-catalyzed Csp2–Csp2 bond forming reactions through C–H activation are still one of the most useful strategies for the diversification of heterocyclic moieties using various coupling partners.
Alexandra Pacheco-Benichou   +4 more
semanticscholar   +1 more source

Studies with Azinylacetonitriles: 2-Pyridylacetonitrile as a Precursor to Functionally Substituted Pyridines

open access: yesMolecules, 2009
2-Pyridylacetonitrile (1) couples with aromatic diazonium salts to yield arylhydrazones 2a-c, that were shown to exist in the syn-form 2 rather than the anti-form 4.
Mohamed Hilmy Elnagdi   +1 more
doaj   +1 more source

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