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Aza‐Diphosphazenanes: Inorganic Cyclohexane‐like Connectors with Stereochemically Tunable Exit Vectors for Molecular and Macromolecular Chemistry

open access: yesAngewandte Chemie, EarlyView.
New aza‐diphosphinanes have been prepared and a model has been developed to explain their cis/trans isomerization. Two‐fold oxidation leads to new aza‐diphosphazenanes as robust inorganic connectors with selectable stereochemistry. Polycondensation reactions results in the first inorganic cyclo‐linear polyphosphazenes which have high‐molecular weights ...
Michael A. Land   +4 more
wiley   +1 more source

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