Results 131 to 140 of about 145,241 (196)

Unlocking Methane Generation via Photo‐Thermal‐Coupled CO2 Hydrogenation by Integrating FeNiCrMnCo Multicomponent Alloy with GaN Nanowires

open access: yesAdvanced Science, EarlyView.
A noble‐metal‐free FeNiCrMnCo multicomponent alloy (MCA) integrated with GaN nanowires achieves efficient photo‐thermal‐coupled CO₂ methanation, delivering a methane production rate of 199 mmol∙g−¹∙h−¹ with 93% selectivity. The system demonstrates exceptional stability and tunable catalytic properties, offering a sustainable pathway for solar‐driven ...
Muhammad Salman Nasir   +9 more
wiley   +1 more source

Non‐Respiratory Extracellular Electron Transfer Competes with Nitrogenase for Electrons in Rhodopseudomonas Palustris

open access: yesAdvanced Science, EarlyView.
This study develops a photosynthetic bioelectrochemical nitrogen fixation system for simultaneous nitrogen fixation and current generation using Rhodopseudomonas palustris. Notably, extracellular electron transfer (EET) serves as a redox balancing strategy, suppressing nitrogen fixation by competing with nitrogenase for electrons.
Xuewen Liu   +6 more
wiley   +1 more source

Surface Charge Transfer Enhanced Cobalt‐Phthalocyanine Crystals for Efficient CO2‐to‐CO Electroreduction with Large Current Density Exceeding 1000 mA cm−2

open access: yesAdvanced Science, EarlyView.
A spray‐growth method is developed to rapidly load cobalt‐phthalocyanine crystals onto carbon paper (CoPc/CP). The electrode maintains > 90% CO selectivity across potentials (−0.57–−1.32 V vs. RHE), achieving a record JCO (−1034 mA cm−2), ultra‐high mass activity (5180 A g−1), and excellent stability (145 h@−150mA cm−2), surpassing all reported Pc ...
Tengyi Liu   +10 more
wiley   +1 more source

Single Cu Atoms Anchored Energetic COFs as Combustion Catalytic Promoters toward Rapid and Concentrated Thermal Decomposition of Ammonium Perchlorate

open access: yesAdvanced Science, EarlyView.
Introducing energetic Cu‐based metal salts into the covalent organic frameworks (COFs) structure, Cu is in single‐atom form anchored to the framework, with energetic anions confined in the COFs structure. The synergistic interaction between single Cu atoms and the anions accelerates the reaction kinetics of ammonium perchlorate (AP) decomposition ...
Meng Zhang   +8 more
wiley   +1 more source

Hydrocyclization/Defluorination of CF3‐Substituted Acrylamides: Insights from Kinetics of Hydrogen Atom Transfer

open access: yesAdvanced Science, EarlyView.
The study develops a H•/H– transfer strategy enabling efficient hydrocyclization/defluorination of CF3‐acrylamides to synthesize Seletracetam derivatives with gem‐difluoroalkenes. Mechanistic studies reveal distinct pathways: the NiII‐H/PhSiH3 system operates through a hydrogen atom transfer process, while the 1,4‐Michael addition of H– appears to be ...
Yanjun Wan, Ronghui Shao, Jack R. Norton
wiley   +1 more source

Breath Fingerprint of Colorectal Cancer Patients Based on the Gas Chromatography-Mass Spectrometry Analysis. [PDF]

open access: yesInt J Mol Sci
Kononova E   +11 more
europepmc   +1 more source

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