Results 221 to 230 of about 313,673 (292)

A Degradable Device for Sustainable Capillary Blood Sampling

open access: yesAdvanced Materials Technologies, EarlyView.
The device features a compostable 3D‐printed storage compartment for liquid blood collection and a degradable, poly(ɛ‐caprolactone)‐coated magnesium microneedle patch hidden within a suction cup. Manual compression deploys the MNs, creating small skin punctures, and the subsequent release of compression generates the negative pressure required for ...
Nicole Zoratto   +5 more
wiley   +1 more source

A Dual‐Emissive DNA‐Templated Silver Nanocluster with Near‐Infrared I and II Emission

open access: yesAdvanced Optical Materials, Volume 13, Issue 8, March 13, 2025.
This study presents a dual‐emissive DNA‐stabilized silver nanocluster with a nanosecond‐lived NIR‐I emission band and a microsecond‐lived NIR‐II emission band. Mass spectrometry establishes that the nanocluster has molecular formula (DNA)2[Ag17]11+. DNA sequence variations reveal critical nucleobases for stabilization, and modifications at the DNA 5 ...
Anna Gonzàlez‐Rosell   +6 more
wiley   +1 more source

Applications of QSPR and Machine Learning in Molecular Photonics

open access: yesAdvanced Optical Materials, EarlyView.
Quantitative structureproperty relationships (QSPR) and machine learning (ML) are transforming photochemistry by enabling pre‐synthetic screening of photoactive molecules. This review outlines advances in data‐driven discovery of optical materials and functional dyes, identifies effective descriptors and models for photophysical processes, and provides
Andrey A. Buglak   +2 more
wiley   +1 more source

Ultrashort‐Pulsed Laser Diffusion Enhancement in Liquids for Cold Extraction of Coffee in an Analytically Validated Low‐Fluence Regime

open access: yesAdvanced Photonics Research, EarlyView.
In this article, pulsed laser diffusion enhancement in liquids as an analytically validated laser extraction in liquids method of coffee suspensions in a defined low fluence window is presented. The results confirm the generation of a unique aroma profile and reduced acidity, which is neither attributed to changes in the specific surface area nor ...
Tina Friedenauer   +15 more
wiley   +1 more source

Water‐Mediated 1,7‐Palladium Aryl‐to‐Aryl Migration in an Unusual Aryne Trimerization Enables the Synthesis of Multihelicenes with Profoundly Hindered Stereogenic Axes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
In the presence of a Pd0 catalyst, large π‐extended arynes trimerize in an unusual manner to forge extremely compact and strained chiral benzenoids. This new trimerization reaction involves a 1,7‐Pd isomerization, a rare and poorly understood process that is elucidated.
Albert Artigas   +6 more
wiley   +1 more source

Cooperative Photocatalysis of 9,10‐Phenanthrenequinone and Sn(OTf)2 for Direct Mannich Reaction of Ethers via Hydrogen Atom Transfer Pathway

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A dual photocatalytic system of o‐PQ and Sn(OTf)2 enables visible light‐induced Mannich‐type addition of ethers to nitrones via Csp³–H activation. This oxidant‐free method offers broad scope and good yields. Mechanistic studies suggest that a photoexcited o‐PQ–Sn(II) complex mediates hydrogen atom transfer to form α‐oxy radicals for nitrone addition. A
Pradip Ramdas Thorve   +2 more
wiley   +1 more source

Thioether Synthesis via the Nickel‐Catalyzed Electrochemical Cross Electrophile Coupling of Aryl/Alkyl Disulfides and Aryl/Alkyl Halides

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A nickel catalyzed electrochemical cross‐electrophile coupling approach for the base‐free synthesis of (un)symmetric (hetero)aryl and alkyl sulfides from organic halides and disulfides is described. The reaction is broadly applicable and tolerates water and air atmosphere. A formal cross‐electrophile coupling approach enables the base‐free synthesis of
Jona Queder, Gerhard Hilt
wiley   +1 more source

Recent Advances in Ene Reactions with Carbon Enophiles

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Recent advances in the classical intra‐ and intermolecular ene nexus with carbon enophiles (alkenes, alkynes, arynes, and allenes) show a considerable increase in structural complexity and an enormous potential for functional applications in polymer science.
Thomas J. J. Müller
wiley   +1 more source

Highly Sensitive Detection of Human Serum Albumin Biomarker Using a Molecularly Imprinted Polymer‐Based Electrochemical Capacitance Sensor

open access: yesAdvanced Sensor Research, EarlyView.
An electrosynthesized protein‐imprinted polymer (poly(azo‐BBY)) enables probe‐free, real‐capacitance detection of human serum albumin at 0.02 ng mL−1 within a 0.25–3.0 ng mL−1 window. The device uses a redox‐mediator‐free architecture and maintains selectivity against common interferents, illustrating a simple, scalable route to high‐sensitivity ...
Heitor F. Trevizan   +4 more
wiley   +1 more source

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