Results 241 to 250 of about 741,703 (306)

In Situ Photopolymerization of Smectic B Liquid‐Crystalline Electrolytes from Mesogenic Phosphate–Diacrylate/Ionic Liquid Complexes for High‐Performance Soft Ionic Actuators

open access: yesAdvanced Robotics Research, EarlyView.
A flexible liquid‐crystalline electrolyte membrane via in situ photopolymerization of a phosphate‐functionalized mesogen, ionic liquid, and diacrylate monomer is developed. The resulting smectic B (SmB)‐phase structure enables 2D ion transport with high conductivity (10−4 S cm−1).
Chengyang Liu, Masafumi Yoshio
wiley   +1 more source

Chiral Potassium Brønsted Base‐Catalyzed Stereoselective Synthesis of 1,3‐Diols via a Tandem Allylic Isomerization/Asymmetric Aldol–Tishchenko Reaction

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Chiral potassium base catalysts featuring 1,1´‐bi‐2‐naphthol‐derived chiral crown ethers as ligands promote a tandem allylic isomerization/asymmetric aldol‐Tishchenko reaction of allylic alcohols and aldehydes. This method provides enantioenriched 1,3‐diols with excellent diastereoselectivity and high enantioselectivity, thereby expanding the synthetic
Hiroki Ishikawa, Masahiro Sai
wiley   +1 more source

Exploring the Uncharted Indolizine Chemical Space: Construction of 5‐Acylindolizines via a Domino Aldol–Vinylogous Aldol Process

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A domino aldol condensation–intramolecular vinylogous aldol condensation process was implemented for the first time to enable access to a wide range of novel 5‐acylated indolizines with a hydrogen, an alkyl, an aryl, or an alkoxy moiety at the C7 site.
Dohui Ku, Sunhee Lee, Ikyon Kim
wiley   +1 more source

RePol: A high-throughput screen for optimizing membrane protein solubilization and purification using polymers. [PDF]

open access: yesProtein Sci
Evans A   +7 more
europepmc   +1 more source

Harnessing Carbenoid Reactivity From Imidazoles and Oxiranes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
The combination of azole compounds and oxiranes exhibits carbenoid reactivity at elevated temperatures, as demonstrated by the successful benzoin condensation of aromatic aldehydes. Using this catalytic system to polymerize bifunctional aldehyde/oxirane monomers yields thermosets with glass transition temperatures above 100°C.
Matthias R. Steiner   +4 more
wiley   +1 more source

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