Results 281 to 290 of about 711,942 (356)

Interior and Exterior Boron Doping in Functional Azacalixarenes Triggering Narrowband Delayed Fluorescence

open access: yesAdvanced Optical Materials, EarlyView.
A unique regioselective interior/exterior borylation strategy is presented for the one‐shot synthesis of two distinct organoboron luminophores from a common macrocyclic azacalix[3]arene. This interior/exterior borylation imparts the material with remarkable TADF properties and narrowband emission capabilities, spanning the violet to blue spectral ...
Sudhir K. Keshri   +2 more
wiley   +1 more source

Water‐Mediated 1,7‐Palladium Aryl‐to‐Aryl Migration in an Unusual Aryne Trimerization Enables the Synthesis of Multihelicenes with Profoundly Hindered Stereogenic Axes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
In the presence of a Pd0 catalyst, large π‐extended arynes trimerize in an unusual manner to forge extremely compact and strained chiral benzenoids. This new trimerization reaction involves a 1,7‐Pd isomerization, a rare and poorly understood process that is elucidated.
Albert Artigas   +6 more
wiley   +1 more source

Chemoselective Synthesis of α‐Chloro and α,α‐Dichloro Acetamidines via the Carbenoids Addition to Inherently Low Electrophilic Carbodiimides

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Carbodiimides act as competent electrophilic synthons for the chemoselective addition of lithium mono‐ and di‐halocarbenoids. The transformation is provided through a single synthetic operation—hitherto elusive—halogenated acetamidines. Interestingly, the constitutively tamed electrophilicity of the starting materials is effectively counterbalanced by ...
Davide Castiglione   +4 more
wiley   +1 more source

Oxa-Ferrier Rearrangement Reaction Mediated by TEMPO Cation and NaClO<sub>2</sub>: Application to the Total Synthesis of Passifetilactones B and C. [PDF]

open access: yesJ Org Chem
Bautista-Nava J   +5 more
europepmc   +1 more source

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