Results 101 to 110 of about 50,405 (263)

Photoresponsive Adaptive Reconfiguration of Single‐Atom Interface With Intermittent Light and Soft Ionic Lattices

open access: yesAdvanced Materials, EarlyView.
We present a photoresponsive platform that integrates SACs with halide perovskite supports, turning perovskite ion mobility, typically a stability concern, into a functional mechanism for light‐regulated self‐repair and reversible atomic reconfiguration. Adaptive metal‐support interactions are established through bandgap‐funnel engineering and the soft
Li Yu   +10 more
wiley   +1 more source

Ga‐on‐In Substitution with Zn Vacancies in Zn3In2S6 Induces Electron–Hole Asymmetry and In─O Bond Weakening for Coupled Two‐Electron Oxygen Reduction and H2O2 Stabilization

open access: yesAdvanced Materials, EarlyView.
Ga‐on‐In substitution coupled with Zn vacancies in Zn3In2S6 creates a dopantdefect synergy that weakens InO bonding and induces electronhole asymmetry. The resulting spatial charge separation directs the two‐electron oxygen reduction pathway, enabling efficient artificial photosynthesis of H2O2 with a production rate of 187.8 µmol g−1 min−1 ...
Xiaowen Ruan   +10 more
wiley   +1 more source

partial molar Gibbs energy

open access: yes, 2014
Citation: 'partial molar Gibbs energy' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.P04417 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

Activating a Metallization Switch for Record Hydrogen Evolution in Single‐Atom Modified Polar MOF Piezocatalysts

open access: yesAdvanced Materials, EarlyView.
ABSTRACT Piezocatalytic hydrogen evolution enables the conversion of mechanical energy into chemical fuels, but its efficiency is constrained by a trade‐off between piezoelectric polarization and electronic conductivity. Strong piezoelectric polarization is essential for sufficient driving force, yet highly polar materials typically suffer from poor ...
Chongyan Hao   +13 more
wiley   +1 more source

Oxygen Evolution Reaction Catalysts for Acidic‐Media CO2 Electrolyzers

open access: yesAdvanced Materials, EarlyView.
Acidic‐media CO2 electroreduction (CO2R) could decarbonize chemical production, despite relying on rare‐earth elements for anodic oxygen evolution reaction (OER). Transferring the learnings from mature sister technologies (water electrolysis) could accelerate technological development.
Mingcheng Huang, Adnan Ozden
wiley   +1 more source

Inter‐Atomic Synergy on Single‐Atom Alloy Promotes Cyclohexanone Oxime Electrosynthesis

open access: yesAdvanced Materials, EarlyView.
Electrosynthesis of cyclohexanone oxime using renewable electricity offers a greener alternative to traditional energy‐intensive methods. Here, we develop a Fe1Bi single‐atom alloy that delivers 70.9% Faradaic efficiency and 0.94 mmol cm−2 h−1 yield rate through the atomic‐scale synergistic mechanism.
Panlong Zhai   +10 more
wiley   +1 more source

Undercoordinated Molybdenum Catalysts Enable Ultrafast Quasi‐Solid Sulfur Chemistry in Sodium‐Sulfur Batteries

open access: yesAdvanced Materials, EarlyView.
An unsaturated coordination chemistry strategy activates a quasi‐solid‐state redox pathway by strengthening NaPSs adsorption and accelerating redox conversion kinetics, thereby overcoming the kinetic bottlenecks that limit high‐rate performance. In situ transmission electron microscopy, combined with newly developed Na‐ion diffusion descriptors ...
Mingyue Wang   +12 more
wiley   +1 more source

Phase Diagrams Enable Solid‐State Battery Design

open access: yesAdvanced Materials Interfaces, EarlyView.
Batteries are non‐equilibrium devices with inherent thermodynamic driving forces to react at interfaces, regardless of kinetics or operating conditions. Chemical potential mismatches across interfaces are dissipated via interfacial reactions. In this work, it is illustrated how phase diagrams and chemical potential maps predict degradation pathways but
Nathaniel L. Skeele, Matthias T. Agne
wiley   +1 more source

Photocatalytic Water Splitting on the Lunar Surface: Prospects for In Situ Resource Utilization

open access: yesAdvanced Materials Interfaces, EarlyView.
Water has been found in craters on the moon nearby locations which are illuminated >80% of the time. Photocatalysis uses energy from sunlight to drive chemical reactions such as water splitting to produce oxygen and hydrogen. It is a scalable technology that requires lighter equipment and utilizes resources available on the moon. ABSTRACT The discovery
Ranjani Kalyan   +6 more
wiley   +1 more source

Home - About - Disclaimer - Privacy