Results 131 to 140 of about 1,741 (266)

Ligand Redox Noninnocence in Bis(phosphinimine) Diarylamido Pincer Complexes of Nickel

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
The oxidative noninnocence of a bis(phosphinimine) ligand featuring a diarylamido backbone was investigated for several nickel complexes. Radical/charge delocalization across the aromatic backbone plays an important role in the stabilization of the diarylaminyl and putative diarylnitrenium complexes.
Xiujing Xing   +8 more
wiley   +1 more source

Persistent influence of the North Atlantic Oscillation on Late Holocene hydroclimate in southwestern Greenland. [PDF]

open access: yesNat Commun
Faust JC   +13 more
europepmc   +1 more source

Synthesis of Cysteine–Fluorophore Conjugates by Visible‐Light‐Promoted Thiol–Ene Coupling Using Organic Photocatalysts

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Cysteine–fluorophore conjugates were efficiently prepared through a visible‐light‐driven thiol–ene approach employing solely organic photocatalysts. The reaction proceeds under mild, metal‐free conditions. The fluorophore scope includes mono‐ and dialkene‐functionalized naphthalene, naphthalimide, and aromatic diimide derivatives.
Julieth Bellaizac‐Riascos   +4 more
wiley   +1 more source

Hydrogen Sulfide Application Reduces Postharvest Weight Loss in Tomato Fruit by Promoting Cuticular Wax Accumulation

open access: yesFuture Postharvest and Food, EarlyView.
NaHS‐derived H2S enhances postharvest tomato fruit storability by reducing weight loss, delaying peel wrinkling, and maintaining peel firmness. This response is associated with increased cuticular wax deposition and upregulation of wax biosynthetic and regulatory genes, without marked changes in PME or PG activities. ABSTRACT During postharvest storage,
Yuting Liang   +11 more
wiley   +1 more source

Heterogeneous Exhumation Mechanisms in Neoproterozoic Collisional Metamorphism: P–T Constraints From Pelotas and Punta del Este Terranes, Southern Brazil and Uruguay

open access: yesGeological Journal, EarlyView.
Petrography, thermobarometry, and pseudosection modelling reveal peak metamorphic conditions of 3–7.5 kbar and 520°C–800°C in Tonian‐Cryogenian orthogneisses of the Dom Feliciano Belt. Metamorphic field gradients of 27°C/km–39°C/km and variable exhumation mechanisms support correlation of these units as remnants of a Himalayan‐type Piratini Orogeny ...
Thaiane Niederauer‐Santos   +6 more
wiley   +1 more source

Hard rocks and deep wetlands beneath Thwaites Glacier in Antarctica. [PDF]

open access: yesCommun Earth Environ
Zeising O   +6 more
europepmc   +1 more source

Bryozoan‐Rich Carbonate Units of the Erfoud Area (SE Morocco) Record Latest Katian to Early Hirnantian Interglacial Intervals

open access: yesGeological Journal, EarlyView.
In this study, we re‐examine the depositional architecture of the Erfoud limestone in Morocco. Introducing new biostratigraphic constraints from chitinozoan assemblages, we show that Katian to Hirnantian bryozoan‐pelmatozoan meadows reflect flooding events linked to a series of interglacial transgressions known to have occurred immediately prior to the
Philippe Razin   +4 more
wiley   +1 more source

Modeling the impacts of grazing management on livestock behavior and performance: A case study in the Peruvian Andes

open access: yesGrassland Research, EarlyView.
Our modeling study shows that livestock management strongly influences grazing behavior and animal performance in the Peruvian Andes. Furthermore, adjusting stocking rates and improving animal distribution can enhance forage intake and body condition while increasing forage biomass.
Melody R. Zarria Samanamud   +1 more
wiley   +1 more source

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