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Influence of preparation pathway on the glass forming ability
International Journal of Pharmaceutics, 2017The glass forming ability (GFA), i.e. the ease of amorphization of drugs, is mostly investigated using the critical cooling rate upon melt quenching to generate an amorphous product via the thermodynamic pathway. However, amorphous materials can also be prepared via the kinetic pathway by milling.
Blaabjerg, Lasse Ingerslev +4 more
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Thermodynamic and Viscous Behaviour of Glass Forming Melts and Glass Forming Ability
AIP Conference Proceedings, 2010The bulk metallic glasses (BMGs) have achieved a great interest due to their scientific and potential technological applications and these are among the most extensively studied advanced materials. The understanding of the glass forming ability (GFA) of these multicomponent metallic alloys is an essential parameter to develop new non‐crystalline ...
K. S. Dubey, Arun Pratap, N. S. Saxena
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Evaluation Of Glass-Forming Ability
2008Bulk Metallic Glasses explores an emerging field of materials known as bulk metallic glasses. It summarizes the rapid development of these materials over the last decade and includes documentation on diverse applications of bulk metallic glasses; from structural applications to microcomponents.
Z. P. Lu, Y. Liu, C. T. Liu
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Reduced glass transition temperature and glass forming ability of bulk glass forming alloys
Journal of Non-Crystalline Solids, 2000Abstract Onset temperature (solidus) T m and offset temperature (liquidus) T l of melting of a series of bulk glass forming alloys based on Zr, La, Mg, Pd and rare-earth elements have been measured by studying systematically the melting behaviour of these alloys using DTA or DSC. Bulk metallic glass formation has been found to be most effective
Lu, Z.P., Li, Y., Ng, S.C.
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On The Glass Forming Ability Criteria Of Bulk Metallic Glasses
MRS Proceedings, 2002ABSTRACTA new criterion γ, defined as Tx/(Tg+Tl) (where Tx is the onset crystallization temperature, Tg the glass transition temperature and Tl the liquidus temperature), has been proposed for glass formation in bulk metallic glasses (BMGs). The interrelationship between this new parameter and glass-forming ability (GFA) was elaborated and discussed in
Z. P. Lu, C. T. Liu
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Glass-forming ability of rare earths in fluorozirconate glasses
Journal of Non-Crystalline Solids, 1994Abstract The effects of rare earth elements on glass formation regions in the systems ZrF 4 BaF 2 LnF 3 AlF 3 (Ln is a rare earth element and AlF 3 concentration is 4 mol%) has been examined. It is found that glass formation regions gradually shift to higher concentrations of rare earth fluoride with decreasing rare earth element radius.
N.V. Gur'ev +5 more
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Glass forming ability and thermal stability of oxyfluoride glasses
Journal of Thermal Analysis and Calorimetry, 2009New oxyfluoride glasses based on the system ZrO2-Pr2O3-ZrF4-BaF2 were obtained, and the glass forming ability of this system was evaluated. The effects of glass composition on both thermal stability and the crystalline phases formed upon heat treatment were determined by the DSC and XRD methods, respectively.
A. R. Marquesi +2 more
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Glass-forming ability of butanediol isomers
Journal of Thermal Analysis and Calorimetry, 2010In this study, the thermal behavior of butanediol isomers is investigated for temperatures ranging from 103 to 303 K using differential scanning calorimetry, complemented, when necessary, by polarized light thermal microscopy. The butanediol isomers display quite different thermal behaviors: for 1,2- and 1,3-isomers, glass transition is the only ...
Teresa M. R. Maria +2 more
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The effect of Y on glass forming ability
Scripta Materialia, 2005Abstract We have discovered a new glass forming region (GFR) defined by melt-spinning at a speed of 30 m/s in a ternary Fe–Fe2B–Fe4B4Y eutectic in the Fe–B–Y alloy system. This GFR is remarkably wide, within the compositional range 19–40 at.% B, 3 to ∼10 at.% Y and 76–50 at.% Fe, with the best glass former being Fe71.2B24Y4.8 for a 1 mm fully ...
Zhang, J., Tan, H., Feng, Y.P., Li, Y.
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Alloys of high glass-forming ability
Journal of Non-Crystalline Solids, 1996Abstract A series of Zr-Ti-Al-Cu-Ni alloys, e.g., Zr 57 Ti 5 Al 10 Cu 20 Ni 8 , were found to have high glass-forming ability (GFA). Cylindrical bulk amorphous samples with diameters of 10 mm were produced by casting the melts in a copper mould. The Zr 65 Cu 17.5 Ni 10 Al 7.5 alloy, which was reported to have the highest GFA heretofore, was found to
L.Q. Xing +4 more
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