Syntheses and luminescent properties of a series of new lanthanide azelates [PDF]
A series of new lanthanide azelates [Ln(aze)(Haze)(H2O)]·H2O {Ln = La (1a), Ce (1b), Pr (1c); H2aze = azelaic acid}, [Ln2(aze)3(phen)2]·H2O [Ln = Nd (2a), Er (2b); phen = 1,10-phenanthroline], [Sm(aze)(Haze)(phen)]·2H2O (3), [Gd(aze)(phen)2]·ClO4 (4) and
Fu, Lianshe +4 more
core +1 more source
Adaptive resistance is not responsible for long-term drug resistance in a cellular model of triple negative breast cancer [PDF]
Resistance to cancer therapeutics represents a leading cause of mortality and is particularly important in cancers, such as triple negative breast cancer, for which no targeted therapy is available, as these are only treated with traditional ...
Castellanos-Uribe, M +3 more
core +2 more sources
New Catalytic Systems for Fixation of Carbon Dioxide into Valuable Poly(Alkylene Carbonates) [PDF]
Fixation of carbon dioxide into valuable products is a promising method to mitigate the issues of global warming and decrease the consumption of fossil-fuel carbon sources.
Bahramian, Bahareh, Dehghani, Fariba
core +2 more sources
Di-μ-glutarato-κ4 O 1:O 5-bis[aqua(1,10-phenanthroline-κ2 N,N′)copper(II)] [PDF]
In the centrosymmetric dinuclear title complex, [Cu2(C5H6O4)2(C12H18N2)2(H2O)2], the CuII atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two phenanthroline N atoms and two O atoms from different ...
Farrugia +9 more
core +3 more sources
Conversion of lanthanide glutarate chlorides with interstitial THF into lanthanide glutarates with unprecedented topologies [PDF]
Using slow diffusion methods at room temperature (RT), we obtained four isomorphous lanthanide glutarate chlorides, accommodating interstitial THF and water molecules, [Ln2(Glut)2Cl2(H2O)8]•2H2O•THF (1 - 4), with Ln = La (1), Ce (2), Pr (3), Nd (4). They
Dempsey, Christian +7 more
core +1 more source
An Efficient Process for Pretreatment of Lignocelluloses in Functional Ionic Liquids [PDF]
Background and Aims. The complex structure of the lignocelluloses is the main obstacle in the conversion of lignocellulosic biomass into valuable products. Ionic liquids provide the opportunities for their efficient pretreatment for biomass.
Bi-Xian Zhang +3 more
core +2 more sources
Desymmetrization of meso-methylenecyclopropanes by a palladium-catalyzed asymmetric ring-opening bis(alkoxycarbonylation) reaction [PDF]
Desymmetrization of various meso-methylenecyclopropanes was accomplished by a palladium-catalyzed asymmetric ring-opening bis(alkoxycarbonylation) reaction employing a chiral bioxazoline ligand. The reaction proceeded smoothly in the presence of copper(I)
Aratani Takahiro +5 more
core +2 more sources
Osteosarcoma is the most common primary bone tumor with limited treatment options and a terrible prognosis. This review provides a comprehensive summary of the recent development of osteoimmunomodulatory implants for post‐operative osteosarcoma treatment, of which the potential utility in evoking durable anti‐osteosarcoma immunity and accelerating bone
Yilong Dong +6 more
wiley +1 more source
This study identifies Pirin (PIR), an iron‐binding protein, as a critical ferroptosis suppressor in colorectal cancer through lipid membrane remodeling. PIR, induced by NRF2 during ferroptotic stress, transcriptionally regulates PLA2G4A to shift cellular lipid composition away from ferroptosis‐permissive polyunsaturated phospholipids.
Wei Shi +10 more
wiley +1 more source
ABSTRACT Cytosolic phosphoenoylpyruvate carboxykinase (PEPCK‐C) is an essential, rate‐limiting enzyme in the gluconeogenesis pathway. PEPCK‐C deficiency presents with hypoglycaemia, hyperlactataemia and hepatopathy, and was first reported in association with bi‐allelic PCK1 variants in 2014.
Isaac Bernhardt +9 more
wiley +1 more source

