Catalytic Performance of Li/Mg Composites for the Synthesis of Glycerol Carbonate from Glycerol and Dimethyl Carbonate [PDF]
ACS Omega, 2022 A series of Li/Mg composites were synthesized by the coprecipitation method using magnesium and lithium nitrates, and then used for the synthesis of glycerol carbonate (GC) from glycerol and dimethyl carbonate (DMC). The experimental results indicated that Li/Mg composites were prospective catalysts for GC synthesis.
Zhenmin Liu +11 more
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Synthesis of Glycerol Carbonate from Ethylene Carbonate Using Zinc Stearate as a Catalyst: Operating Conditions and Kinetic Modeling [PDF]
Molecules, 2023 With the advent of biodiesel as a substitute/additive for diesel, the production of glycerol has experienced an increase, as it is an unavoidable byproduct of the biodiesel process; therefore, novel products and processes based on this triol are being ...
Mariana Alvarez Serafini +4 more
doaj +2 more sources
Synthesis of Hydrotalcites from Waste Steel Slag with [Bmim]OH Intercalated for the Transesterification of Glycerol Carbonate [PDF]
Molecules, 2020 Ca-Mg-Al hydrotalcites were prepared by coprecipitation from Type S95 steel slag of Shanghai Baosteel Group as supports of ionic liquid in this paper. Five basic ionic liquids [Bmim][CH3COO], [Bmim][HCOO], [Bmim]OH, [Bmim]Br and ChOH were prepared and ...
Guanhao Liu, Jingyi Yang, Xinru Xu
doaj +2 more sources
Ultrasound-Assisted Synthesis of Glycerol Carbonate Using Potassium-Modified Silicalite-1 as a Catalyst [PDF]
MoleculesThis study investigates the use of potassium-modified silicalite-1 as a catalyst for the transesterification of glycerol to glycerol carbonate (Glyc. Carbonate) with dimethyl carbonate (DMC).
Jolanta Kowalska-Kuś +5 more
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A Green Approach to Obtaining Glycerol Carbonate by Urea Glycerolysis Using Carbon-Supported Metal Oxide Catalysts [PDF]
Molecules, 2023 The results of sustainable and selective synthesis of glycerol carbonate (GC) from urea and glycerol under ambient pressure using carbon-fiber-supported metal oxide catalysts are reported.
Karolina Ptaszyńska +3 more
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Transesterification of Glycerol with Dimethyl Carbonate to Glycerol Carbonate over Na–based Zeolites [PDF]
Chinese Journal of Catalysis, 2012 Abstract Glycerol carbonate (GC) was synthesized via transesterification of glycerol with dimethyl carbonate under mild conditions over a series of base zeolites. It was found that the NaY zeolite exhibited a higher selectivity for GC (100%) than heterogeneous bases (such as CaO and SrO) or homogeneous catalysts (such as NaOH and K2CO3).
Renfeng Nie, Saiyong Pan, Zhaoyin Hou
exaly +2 more sources
Review of Glycerol Conversion to Glycerol Carbonate via Alkyl Carbonates: Reflections, Future Perspective and Catalytic Roles of Mixed/Promoted Metal Oxides and Mechanistic Insights from DFT [PDF]
MoleculesThis review summarizes recent progress in the catalytic conversion of glycerol to glycerol carbonate (GC) via transesterification with alkyl carbonates, a sustainable route for valorizing surplus glycerol from biodiesel production.
Sakhile T. Dube +2 more
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The Synthesis of Glycerol Carbonate from Glycerol and Carbon Dioxide over Supported CuO-Based Nanoparticle Catalyst. [PDF]
Molecules, 2023 A series of supported CuO-based nanoparticle catalysts were prepared by impregnation method and used for the synthesis of glycerol carbonate from glycerol and CO2 in the presence of 2-cyanopyridine as a dehydrant and DMF as a solvent. The effects of supports (activated alumina, silicon dioxide, graphene oxide, graphene, and activated carbon), CuO ...
Al-Kurdhani JMH, Wang H.
europepmc +4 more sources
ZnO/SiO2 Composite as Catalyst for the Transformation of Glycerol to Glycerol Carbonate ol Carbonate
Makara Journal of Science, 2020 Zinc oxide/porous silica (ZnO/SiO2) composite was used as a catalyst to transform glycerol to glycerol carbonate (GC), a chemical intermediate and monomer for the synthesis of new functionalized polymers.
Yuni Krisyuningsih Krisnandi +4 more
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Ultrasonics Sonochemistry, 2015 The present work illustrates the transesterification of glycerol to glycerol carbonate (GlyC) from dimethyl carbonate (DMC) using commercial immobilized lipase (Novozym 435) under ultrasonic irradiation. The experiments were performed in a batch reactor placed in an ultrasonic water bath using a sequence of experimental protocol to evaluate the effects
Govind V Waghmare, Virendra K Rathod
exaly +3 more sources